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dc.contributor.author
Capllonch, Maria Concepció
dc.contributor.author
García Raso, Angel
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Terrón, Angel
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Apella, Maria Cristina
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dc.contributor.author
Espinosa, Enrique
dc.contributor.author
Molins, Elies
dc.date.available
2018-03-08T16:45:40Z
dc.date.issued
2001-04
dc.identifier.citation
Capllonch, Maria Concepció; García Raso, Angel; Terrón, Angel; Apella, Maria Cristina; Espinosa, Enrique; et al.; Interactions of d10 metal ions with hippuric acid and cytosine. X-ray structure of the first cadmium (II)-amino acid derivative-nucleobase ternary compound; Elsevier Science Inc; Journal of Inorganic Biochemistry; 85; 2-3; 4-2001; 173-178
dc.identifier.issn
0162-0134
dc.identifier.uri
http://hdl.handle.net/11336/38281
dc.description.abstract
The interactions of Zn(II), Cd(II) and Hg(II) with hippuric acid (hipH) were studied and several novel compounds were synthesized and studied by NMR. Some new metal-hippuric-cytosine ternary compounds were formed and the structure of the [Cd(hip)2(cyt)(H2O)]2 ternary complex resolved. Each cadmium (II) atom has a distorted trigonal bipyramid coordination which is linked to a water molecule, a cytosine via N(3), a carboxylic oxygen atom of a hippurate moiety and two bridging dicoordinated hippurates bound through the carboxylic oxygen atoms. To these five main bonds, two longer ancillary interactions can be observed: the second oxygen of the monocoordinated hippurate group and the carboxylic oxygen of the cytosine ligand. The compound is stabilized by an intramolecular stacking between the benzene and cytosine rings and by the hydrogen bonds between the coordinated water molecules and the ligands. This is, to our knowledge, the first structure of a cadmium-amino acid derivative-natural nucleobase compound described so far.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier Science Inc
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dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Cadmium Complex
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Cytosine
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Hippuric Acid
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Ternary Complexes
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Otras Ciencias Químicas
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dc.subject.classification
Ciencias Químicas
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dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
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dc.title
Interactions of d10 metal ions with hippuric acid and cytosine. X-ray structure of the first cadmium (II)-amino acid derivative-nucleobase ternary compound
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-03-06T17:02:44Z
dc.journal.volume
85
dc.journal.number
2-3
dc.journal.pagination
173-178
dc.journal.pais
Estados Unidos
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dc.description.fil
Fil: Capllonch, Maria Concepció. Universidad de las Islas Baleares; España
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Fil: García Raso, Angel. Universidad de las Islas Baleares; España
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Fil: Terrón, Angel. Universidad de las Islas Baleares; España
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Fil: Apella, Maria Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucuman. Centro de Referencia Para Lactobacilos; Argentina
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Fil: Espinosa, Enrique. Institut de Ciència de Materials; España
dc.description.fil
Fil: Molins, Elies. Institut de Ciència de Materials; España
dc.journal.title
Journal of Inorganic Biochemistry
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dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/S0162-0134(01)00196-9
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0162013401001969
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