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dc.contributor.author
Musci, Juan José
dc.contributor.author
Merlo, Andrea Beatriz
dc.contributor.author
Casella, Mónica Laura
dc.date.available
2018-02-27T16:04:49Z
dc.date.issued
2017-05-05
dc.identifier.citation
Musci, Juan José; Merlo, Andrea Beatriz; Casella, Mónica Laura; Aqueous phase hydrogenation of furfural using carbon-supported Ru and RuSn catalysts; Elsevier Science; Catalysis Today; 296; 1; 5-5-2017; 45-50
dc.identifier.issn
0920-5861
dc.identifier.uri
http://hdl.handle.net/11336/37260
dc.description.abstract
The aqueous phase hydrogenation (APH) of furfural was studied over carbon-supported monometallic Ru and bimetallic RuSn catalysts at 90 °C and 1.25 MPa. Tin was added via Surface Organometallic Chemistry on Metals techniques and its effect was a function of the Sn/Ru atomic ratio. Thus, the addition of Sn in a Sn/Ru ratio of 0.4 promoted the C[dbnd]O hydrogenation reaching a selectivity towards furfuryl alcohol over 85% throughout the course of the reaction. A higher concentration of tin does not improve the situation. It seems to be a compromise between the dilution of Ru sites, active for the hydrogenation reaction, and the promoting effect of Sn. TEM, TPR and XPS characterization indicate the strong interaction between Ru and Sn in all the bimetallic catalysts. Finally, the reuse of the catalyst was analyzed.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier Science
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Aqueous Phase Hydrogenation
dc.subject
Biomass
dc.subject
Furfural
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Rusn
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Surface Organometallic Chemistry
dc.subject.classification
Otras Ingeniería Química
dc.subject.classification
Ingeniería Química
dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
dc.title
Aqueous phase hydrogenation of furfural using carbon-supported Ru and RuSn catalysts
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2017-12-19T18:48:10Z
dc.journal.volume
296
dc.journal.number
1
dc.journal.pagination
45-50
dc.journal.pais
Países Bajos
dc.journal.ciudad
Amsterdam
dc.description.fil
Fil: Musci, Juan José. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro de Investigaciones y Transferencia del Noroeste de la Provincia de Buenos Aires. Universidad Nacional del Noroeste de la Provincia de Buenos Aires. Centro de Investigaciones y Transferencia del Noroeste de la Provincia de Buenos Aires; Argentina
dc.description.fil
Fil: Merlo, Andrea Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
dc.description.fil
Fil: Casella, Mónica Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas ; Argentina
dc.journal.title
Catalysis Today
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.cattod.2017.04.063
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0920586117302961
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