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dc.contributor.author
Franceschini, Fernando C.
dc.contributor.author
Tavares, Tatiana T. Da R.
dc.contributor.author
Dos Santos, João H. Z.
dc.contributor.author
Ferreira, María Luján
dc.contributor.author
Soares, João B.P.
dc.date.available
2018-02-19T17:55:49Z
dc.date.issued
2006-12
dc.identifier.citation
Franceschini, Fernando C.; Tavares, Tatiana T. Da R.; Dos Santos, João H. Z.; Ferreira, María Luján; Soares, João B.P.; Ethylene and propylene polymerization using in situ supported Me 2Si(Ind)2ZrCl2 Catalyst: Experimental and theoretical study; Wiley VCH Verlag; Macromolecular Materials and Engineering (print); 291; 3; 12-2006; 279-287
dc.identifier.issn
1438-7492
dc.identifier.uri
http://hdl.handle.net/11336/36737
dc.description.abstract
Me2Si(Ind)2ZrCl2 was in situ immobilized onto SMAO and used for ethylene and propylene polymerization in the presence of TEA or TIBA as cocatalyst. The catalytic system Me2Si(Ind) 2ZrCl2/SMAO exhibited different behavior depending on the amount and nature of the alkylaluminum employed and on the monomer type. The catalyst activity was nearly 0,4 kg polymer · g cat-1 · h-1 with both cocatalysts for propylene polymerization. Similar activities were observed for ethylene polymerization in the presence of TIBA. When ethylene was polymerized using TEA at an Al/Zr molar ratio of 250, the activity was 10 times higher. Polyethylenes made by in situ supported or homogeneous catalyst systems had practically the same melting point (T m). On the other hand, poly(propylenes) made using in situ supported catalyst systems had a slightly lower Tm than poly(propylenes) made using homogeneous catalyst systems. The nature and amount of the alkylaluminum also influenced the molar mass. The poly(propylene) molar mass was higher when TIBA was the cocatalyst. The opposite behavior was observed for the polyethylenes. Concerning the alkylaluminum concentration, the molar mass of the polymers decreased as the amount of TEA increased. In the presence of TIBA, the polyethylene's molar mass was almost the same, independent of the alkylaluminum concentration, and the poly(propylene) molar mass increased with increasing amounts of cocatalyst. The deconvolution of the GPC curves showed 2 peaks for the homogeneous system and 3 peaks for the heterogeneous in situ supported system. The only exception was observed when TEA was used at an Al/Zr molar ratio of 500, where the best fit was obtained with 2 peaks. Based on the GPC deconvolution results and on the theoretical modeling, a proposal for the active site structure was made.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Wiley VCH Verlag
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Gpc Deconvolution
dc.subject
In Situ Immobilization
dc.subject
Metallocene Catalysts
dc.subject
Modeling
dc.subject.classification
Otras Ingeniería Química
dc.subject.classification
Ingeniería Química
dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
dc.title
Ethylene and propylene polymerization using in situ supported Me 2Si(Ind)2ZrCl2 Catalyst: Experimental and theoretical study
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2017-11-24T13:54:39Z
dc.journal.volume
291
dc.journal.number
3
dc.journal.pagination
279-287
dc.journal.pais
Alemania
dc.journal.ciudad
Weinheim
dc.description.fil
Fil: Franceschini, Fernando C.. Ipiranga Petroquímica S.a.; Brasil
dc.description.fil
Fil: Tavares, Tatiana T. Da R.. Ipiranga Petroquímica S.a.; Brasil
dc.description.fil
Fil: Dos Santos, João H. Z.. Universidade Federal do Rio Grande do Sul; Brasil
dc.description.fil
Fil: Ferreira, María Luján. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
dc.description.fil
Fil: Soares, João B.P.. University Of Waterloo; Canadá
dc.journal.title
Macromolecular Materials and Engineering (print)
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/mame.200500360
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/mame.200500360/abstract
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