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dc.contributor.author
Abraham, Gustavo Abel
dc.contributor.author
Gallardo, Alberto
dc.contributor.author
Mota, Antonella
dc.contributor.author
Migliaresi, Claudio
dc.contributor.author
San Roman, Julio
dc.date.available
2018-02-06T14:15:10Z
dc.date.issued
2000-10-19
dc.identifier.citation
Abraham, Gustavo Abel; Gallardo, Alberto; Mota, Antonella; Migliaresi, Claudio; San Roman, Julio; Microheterogeneuos polymer systems prepared by suspension polymerization of methyl methacrylate in the presence of poly( e-caprolactone); Wiley VCH Verlag; Macromolecular Materials and Engineering (print); 282; 1; 19-10-2000; 44-50
dc.identifier.issn
1438-7492
dc.identifier.uri
http://hdl.handle.net/11336/35734
dc.description.abstract
Poly(methyl methacrylate) – polycaprolactone (PMMA/PCL) microheterogeneous beads were synthesized by suspension polymerization starting from methyl methacrylate (MMA) monomer and PCL, which was synthesized by ring-opening polymerization of ε-caprolactone using ZnCl2 as initiator. The resulting polymer was fully characterized by 1H and 13C NMR, differential scanning calorimetry (DSC), gel permeation chromatography (GPC) and dynamic mechanical thermal analysis (DMTA). The size distribution and morphology of the resulting beads were investigated by optical microscopy and scanning electron microscopy (SEM). Moreover, blends of PMMA beads and PCL in different proportions were prepared and the morphology of the films was examined by optical microscopy. The low compatibility between PMMA and PCL was clearly evidenced through these experiments.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Wiley VCH Verlag
dc.rights
info:eu-repo/semantics/restrictedAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject.classification
Físico-Química, Ciencia de los Polímeros, Electroquímica
dc.subject.classification
Ciencias Químicas
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
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Recubrimientos y Películas
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Ingeniería de los Materiales
dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
dc.title
Microheterogeneuos polymer systems prepared by suspension polymerization of methyl methacrylate in the presence of poly( e-caprolactone)
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-02-02T19:44:26Z
dc.journal.volume
282
dc.journal.number
1
dc.journal.pagination
44-50
dc.journal.pais
Alemania
dc.journal.ciudad
Weinheim
dc.description.fil
Fil: Abraham, Gustavo Abel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
dc.description.fil
Fil: Gallardo, Alberto. Instituto de Ciencia y Tecnologia de Polimeros; España
dc.description.fil
Fil: Mota, Antonella. Universita´ di Trento; Italia
dc.description.fil
Fil: Migliaresi, Claudio. Universita´ di Trento; Italia
dc.description.fil
Fil: San Roman, Julio. Instituto de Ciencia y Tecnologia de Polimeros; España
dc.journal.title
Macromolecular Materials and Engineering (print)
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/1439-2054(20001001)282:1<44::AID-MAME44>3.0.CO;2-K
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/1439-2054(20001001)282:1%3C44::AID-MAME44%3E3.0.CO;2-K/full


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