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dc.contributor.author
Pujro Tarquino, Richard Alfonzo
dc.contributor.author
Falco, Marisa Guadalupe
dc.contributor.author
Sedran, Ulises Anselmo
dc.date.available
2018-01-30T15:49:52Z
dc.date.issued
2015-02
dc.identifier.citation
Pujro Tarquino, Richard Alfonzo; Falco, Marisa Guadalupe; Sedran, Ulises Anselmo; Catalytic Cracking of Heavy Aromatics and Polycyclic Aromatic Hydrocarbons over Fluidized Catalytic Cracking Catalysts; American Chemical Society; Energy & Fuels (print); 29; 3; 2-2015; 1543-1549
dc.identifier.issn
0887-0624
dc.identifier.uri
http://hdl.handle.net/11336/34991
dc.description.abstract
The distribution of products in the range of gasoline and middle distillates cuts obtained in the catalytic cracking of heavy aromatics and polycyclic aromatic hydrocarbons over a FCC catalyst was studied. 1-Phenyloctane, biphenyl, fluorene, 9,10-dihydrophenanthrene, naphthalene, phenanthrene, pyrene and benz[a]anthracene were used as model compounds of alkylaromatic, naphthenic-aromatic and polyaromatic hydrocarbons which are present in VGO and residual feedstocks in the FCC process. The catalyst was used in its fresh and equilibrium forms at 450 ºC in a CREC Riser Simulator reactor with reaction times from 2 to 6 s. Thermal cracking reactions overwhelm the catalytic conversion of naphthenic-aromatic compounds such as fluorene and 9,10-dihydrophenanthrene. Under the same conditions, the fresh catalyst was more active than the equilibrium catalyst. The alkylaromatic, naphthenicaromatic and polyaromatic hydrocarbons, showed catalytic conversions which increased,were relatively stable and decreased, respectively, as a function of reaction time. The distribution of products suggested that most important reactions were thermal dehydrogenation, hydrogen transfer, ring opening, cracking and condensation. It was shown that all the model compounds are cracked, yielding particularly benzene in the gasoline range and coke.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
American Chemical Society
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Aromatics
dc.subject
Pah
dc.subject
Lco
dc.subject
Gasoline
dc.subject
Fcc
dc.subject.classification
Otras Ingeniería Química
dc.subject.classification
Ingeniería Química
dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
dc.title
Catalytic Cracking of Heavy Aromatics and Polycyclic Aromatic Hydrocarbons over Fluidized Catalytic Cracking Catalysts
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-01-18T14:39:17Z
dc.journal.volume
29
dc.journal.number
3
dc.journal.pagination
1543-1549
dc.journal.pais
Estados Unidos
dc.journal.ciudad
Washington
dc.description.fil
Fil: Pujro Tarquino, Richard Alfonzo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
dc.description.fil
Fil: Falco, Marisa Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
dc.description.fil
Fil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
dc.journal.title
Energy & Fuels (print)
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/ef502707w
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/10.1021/ef502707w
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