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dc.contributor.author
Da Silva, Salatiel Wohlmuth
dc.contributor.author
Bortolozzi, Juan Pablo
dc.contributor.author
Banus, Ezequiel David
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Bernardes, Andrea Moura
dc.contributor.author
Ulla, Maria Alicia del H.
dc.date.available
2018-01-30T15:47:39Z
dc.date.issued
2016-01
dc.identifier.citation
Da Silva, Salatiel Wohlmuth; Bortolozzi, Juan Pablo; Banus, Ezequiel David; Bernardes, Andrea Moura; Ulla, Maria Alicia del H.; TiO2 thick films supported on stainless steel foams and their photoactivity in the nonylphenol ethoxylate mineralization; Elsevier; Chemical Engineering Journal; 283; 1-2016; 1264-1272
dc.identifier.issn
1385-8947
dc.identifier.uri
http://hdl.handle.net/11336/34988
dc.description.abstract
The main interest in employing a structured catalyst for water treatment processes is to avoid an extra recovering-step of the powder catalyst after concluding the treatment. For this purpose, TiO2 powder (Degussa P25) was immobilized onto metallic foam walls (TiO2-foam) through the washcoating method and its photocatalytic activity was evaluated in the degradation of nonylphenol ethoxylate (NP4EO), which is considered an endocrine disrupter. The morphological and physicochemical characteristics of TiO2 films were studied by X-ray Diffraction, Laser Raman Spectroscopy and Scanning Electron Microscopy. The fast and easy washcoating method used in this work allowed the immobilization of the TiO2 powder onto a relatively inexpensive metallic substrate. The TiO2 layer was uniformly distributed, having a high adherence to the metallic foam walls, which were previously submitted to a passivation treatment. This pre-treatment hindered a further migration of cations from the foam core to the titania film and favored the subsequent film anchorage. Moreover, the catalytic film so obtained maintained the anatase and rutile phases with their original proportions, preserving the properties of the TiO2 powder. The photocatalytic activity of the TiO2-foam was similar to that of a commercial catalyst (TiO2–Ti mesh), i.e. both reduced the TOC of the NP4EO solution by about 91%, showing similar reaction kinetics and overall quantum yield (Фoverall). These results demonstrate that by means of the method under study, TiO2 can be successfully immobilized without decreasing its photocatalytic activity. These catalysts may be applied in water/wastewater treatment, reducing the process stages and the overall cost of the procedure.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Titanium Oxide
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Heterogeneous Photocatalysis
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Emerging Contaminant
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Nonylphenol Ethoxylate
dc.subject.classification
Ingeniería Medioambiental y Geológica, Geotécnicas
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Ingeniería del Medio Ambiente
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INGENIERÍAS Y TECNOLOGÍAS
dc.title
TiO2 thick films supported on stainless steel foams and their photoactivity in the nonylphenol ethoxylate mineralization
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-01-18T14:39:31Z
dc.journal.volume
283
dc.journal.pagination
1264-1272
dc.journal.pais
Países Bajos
dc.journal.ciudad
Amsterdam
dc.description.fil
Fil: Da Silva, Salatiel Wohlmuth. Universidade Federal do Rio Grande do Sul; Brasil
dc.description.fil
Fil: Bortolozzi, Juan Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
dc.description.fil
Fil: Banus, Ezequiel David. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
dc.description.fil
Fil: Bernardes, Andrea Moura. Universidade Federal do Rio Grande do Sul; Brasil
dc.description.fil
Fil: Ulla, Maria Alicia del H.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
dc.journal.title
Chemical Engineering Journal
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1385894715011390
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.cej.2015.08.057
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