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dc.contributor.author
García, Manuela Emila
dc.contributor.author
Woodruff, Shannon R.
dc.contributor.author
Hellemann, Erich
dc.contributor.author
Tsarevsky, Nicolay V.
dc.contributor.author
Gil, Roberto Ricardo
dc.date.available
2018-01-23T17:27:42Z
dc.date.issued
2017-03
dc.identifier.citation
García, Manuela Emila; Woodruff, Shannon R.; Hellemann, Erich; Tsarevsky, Nicolay V.; Gil, Roberto Ricardo; Di(ethylene glycol) methyl ether methacrylate (DEGMEMA)-derived gels align small organic molecules in methanol; John Wiley & Sons Ltd; Magnetic Resonance in Chemistry; 55; 3; 3-2017; 206-209
dc.identifier.issn
0749-1581
dc.identifier.uri
http://hdl.handle.net/11336/34271
dc.description.abstract
Residual dipolar couplings (RDCs) constitute an important NMR parameter for structural elucidation in all areas of chemistry. In this study, di(ethylene glycol) methyl ether methacrylate (DEGMEMA)-basedgelsare introduced as alignment media for the measurement of RDCs of small organic molecules in polar solvents such as methanol. The low viscosity of methanol permits the execution of J-scaled BIRD HSQC experimentsthat yield very sharp lines in anisotropic conditions. The gels have excellent mechanical properties, and their compression and expansion in the swollen state can be reversed and performed multiple times. This process enables the easy loading and release of analytes. The excellent performance of these new aligning gels is demonstrated by analyzing the structure of the alkaloid retrorsine.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
John Wiley & Sons Ltd
dc.rights
info:eu-repo/semantics/restrictedAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
J-Scaled Bird Hsqc
dc.subject
Residual Dipolar Couplings
dc.subject
Degmema Gels
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Alignment Media
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Retrorsine
dc.subject.classification
Química Orgánica
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Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
Di(ethylene glycol) methyl ether methacrylate (DEGMEMA)-derived gels align small organic molecules in methanol
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2018-01-12T19:26:40Z
dc.identifier.eissn
1097-458X
dc.journal.volume
55
dc.journal.number
3
dc.journal.pagination
206-209
dc.journal.pais
Reino Unido
dc.journal.ciudad
Londres
dc.description.fil
Fil: García, Manuela Emila. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina. University Of Carnegie Mellon; Estados Unidos
dc.description.fil
Fil: Woodruff, Shannon R.. University Of Carnegie Mellon; Estados Unidos. Southern Methodist University; Estados Unidos
dc.description.fil
Fil: Hellemann, Erich. University Of Carnegie Mellon; Estados Unidos
dc.description.fil
Fil: Tsarevsky, Nicolay V.. University Of Carnegie Mellon; Estados Unidos
dc.description.fil
Fil: Gil, Roberto Ricardo. University Of Carnegie Mellon; Estados Unidos
dc.journal.title
Magnetic Resonance in Chemistry
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/mrc.4400/full
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/mrc.4400


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