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dc.contributor.author
Azzolina Jury, Federico  
dc.contributor.author
Polaert, Isabelle  
dc.contributor.author
Pierella, Liliana Beatriz  
dc.contributor.author
Estel, Lionel  
dc.date.available
2018-01-17T16:11:44Z  
dc.date.issued
2014-02  
dc.identifier.citation
Azzolina Jury, Federico; Polaert, Isabelle; Pierella, Liliana Beatriz; Estel, Lionel; Optimized benzaldehyde production over a new Co-ZSM-11 catalyst: Reaction parameters effects and kinetics; Elsevier Science; Catalysis Communications; 46; 2-2014; 6-10  
dc.identifier.issn
1566-7367  
dc.identifier.uri
http://hdl.handle.net/11336/33611  
dc.description.abstract
An efficient Co-ZSM-11 catalyst has been synthesized for benzaldehyde production by the selective styrene oxidation. Reaction parameters such as catalyst mass, reaction temperature, molar ratio styrene/hydrogen peroxide and stirring speed were optimized, by performing the styrene oxidation reaction in a stirred batch system with fine particles of Co-ZSM-11 in suspension under microwave heating. A kinetic study was done by using the initial rate method and the Arrhenius parameters were estimated. This catalyst presents a higher reaction rate about 30% with respect of those found in literature and a higher selectivity towards benzaldehyde about 80% at optimal conditions.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Elsevier Science  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/  
dc.subject
Microwave  
dc.subject
Co-Zsm-11  
dc.subject
Styrene Oxidation  
dc.subject
Benzaldehyde  
dc.subject
Kinetic Parameters  
dc.subject.classification
Otras Ciencias Químicas  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
Optimized benzaldehyde production over a new Co-ZSM-11 catalyst: Reaction parameters effects and kinetics  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2018-01-17T15:04:56Z  
dc.journal.volume
46  
dc.journal.pagination
6-10  
dc.journal.pais
Países Bajos  
dc.journal.ciudad
Amsterdam  
dc.description.fil
Fil: Azzolina Jury, Federico. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina. Laboratoire de Sécurité des Procédés Chimiques. Rouen; Francia  
dc.description.fil
Fil: Polaert, Isabelle. Laboratoire de Sécurité des Procédés Chimiques. Rouen; Francia  
dc.description.fil
Fil: Pierella, Liliana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigación y Tecnología Química. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina  
dc.description.fil
Fil: Estel, Lionel. Laboratoire de Sécurité des Procédés Chimiques. Rouen; Francia  
dc.journal.title
Catalysis Communications  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.catcom.2013.11.020  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S1566736713004494