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dc.contributor.author
Bavio, Marcela Alejandra  
dc.contributor.author
Kessler, Teresita  
dc.contributor.author
Castro Luna Berenguer, Ana Maria del Carmen  
dc.date.available
2018-01-15T18:42:51Z  
dc.date.issued
2012-12  
dc.identifier.citation
Castro Luna Berenguer, Ana Maria del Carmen; Kessler, Teresita; Bavio, Marcela Alejandra; Pt-Ru polymeric electrocatalysts used for the determination of carbon monoxide; Elsevier Science; Thin Solid Films; 527; 12-2012; 318-322  
dc.identifier.issn
0040-6090  
dc.identifier.uri
http://hdl.handle.net/11336/33294  
dc.description.abstract
Different PtRu polyaniline composite catalysts were studied for the electro-oxidation of carbon monoxide (CO) in order to ascertain their response to the changes in CO bulk concentration in acid solutions. The catalyst substrate consisted of polyaniline films with incorporated carbon nanotubes grown over a Ni wire. To build the electrode, PtRu particles were added to the polymeric film by immersion at open circuit from a solution containing Pt(IV) and Ru(III). The concentration relationship R = [Pt(IV)]/[Ru(III)] was established fixing the Pt(IV) concentration and varying Ru(III) concentration in order to have 0.5 < R < 5. CO electro-oxidation in acid media was studied applying cyclic voltammetry and chronoamperometry, carefully controlling the amount of CO that flowed into the cell. A linear relationship was established between the CO oxidation current density and its concentration in solution for the catalyst prepared with lower R.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Elsevier Science  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/  
dc.subject
Polimeric Electrodes  
dc.subject
Platinum-Ruthenium  
dc.subject
Carbon Monoxide  
dc.subject.classification
Otras Ciencias Químicas  
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Ciencias Químicas  
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CIENCIAS NATURALES Y EXACTAS  
dc.title
Pt-Ru polymeric electrocatalysts used for the determination of carbon monoxide  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2017-11-10T14:24:30Z  
dc.journal.volume
527  
dc.journal.pagination
318-322  
dc.journal.pais
Países Bajos  
dc.journal.ciudad
Amsterdam  
dc.description.fil
Fil: Bavio, Marcela Alejandra. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ingeniería Olavarría; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina  
dc.description.fil
Fil: Kessler, Teresita. Universidad Nacional del Centro de la Provincia de Buenos Aires. Facultad de Ingeniería Olavarría; Argentina  
dc.description.fil
Fil: Castro Luna Berenguer, Ana Maria del Carmen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina  
dc.journal.title
Thin Solid Films  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.tsf.2012.12.015  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0040609012016501