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dc.contributor.author
Matoz Fernandez, Daniel Alejandro
dc.contributor.author
Ramirez Pastor, Antonio Jose
dc.date.available
2018-01-03T18:46:46Z
dc.date.issued
2014-07
dc.identifier.citation
Ramirez Pastor, Antonio Jose; Matoz Fernandez, Daniel Alejandro; Adsorption preference reversal phenomenon from multisite-occupancy theory for two-dimensional lattices; Elsevier Science; Chemical Physics Letters; 610-611; 7-2014; 131-134
dc.identifier.issn
0009-2614
dc.identifier.uri
http://hdl.handle.net/11336/32155
dc.description.abstract
The statistical thermodynamics of polyatomic species mixtures adsorbed on two-dimensional substrates was developed on a generalization in the spirit of the lattice-gas model and the classical Guggenheim-DiMarzio approximation. In this scheme, the coverage and temperature dependence of the Helmholtz free energy and chemical potential are given. The formalism leads to the exact statistical thermodynamics of binary mixtures adsorbed in one dimension, provides a close approximation for two-dimensional systems accounting multisite occupancy and allows to discuss the dimensionality and lattice structure effects on the known phenomenon of adsorption preference reversal.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier Science
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.subject
Adsorption
dc.subject
Statistical Thermodynamics
dc.subject
Preference Reversal Phenomenon
dc.subject.classification
Astronomía
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Ciencias Físicas
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
dc.title
Adsorption preference reversal phenomenon from multisite-occupancy theory for two-dimensional lattices
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2017-12-12T18:37:13Z
dc.journal.volume
610-611
dc.journal.pagination
131-134
dc.journal.pais
Países Bajos
dc.journal.ciudad
Amsterdam
dc.description.fil
Fil: Matoz Fernandez, Daniel Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
dc.description.fil
Fil: Ramirez Pastor, Antonio Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Física Aplicada ; Argentina
dc.journal.title
Chemical Physics Letters
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0009261414005600
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1016/j.cplett.2014.06.055
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