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dc.contributor.author
Peña, Isabel  
dc.contributor.author
Kolesnikova, Lucie  
dc.contributor.author
Cabezas, Carlos  
dc.contributor.author
Bermudez, Celina  
dc.contributor.author
Berdakin, Matias  
dc.contributor.author
Simao, Alcides  
dc.contributor.author
Alonso, Jose A.  
dc.date.available
2017-12-22T13:01:52Z  
dc.date.issued
2014-09  
dc.identifier.citation
Peña, Isabel; Kolesnikova, Lucie; Cabezas, Carlos; Bermudez, Celina; Berdakin, Matias; et al.; The shape of D-glucosamine; Royal Society of Chemistry; Physical Chemistry Chemical Physics; 16; 9-2014; 23244-23250  
dc.identifier.issn
1463-9076  
dc.identifier.uri
http://hdl.handle.net/11336/31347  
dc.description.abstract
The bioactive amino monosaccharideD-glucosamine has been generated in the gas phasevialaserablation ofD-glucosamine hydrochloride. Three cyclica-4C1pyranose forms have been identified usingFourier transform microwave techniques. Stereoelectronic hyperconjugative forces – essentially linkedwith the anomeric orgaucheeffect – and cooperative OH O, OH N and NH O chains, extendedalong the entire molecule, are found to be the main factors driving the conformational behavior. Theorientation of the NH2group within each conformer has been determined by the values of the nuclearquadrupole coupling constants. The results have been compared with those recently obtained for thearchetypicalD-glucose.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Royal Society of Chemistry  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
Rotational Spectroscopy  
dc.subject
Laser Desorption  
dc.subject
Biomolecules  
dc.subject
D-Glucosamine  
dc.subject.classification
Otras Ciencias Químicas  
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Ciencias Químicas  
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CIENCIAS NATURALES Y EXACTAS  
dc.title
The shape of D-glucosamine  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2017-12-21T16:26:00Z  
dc.journal.volume
16  
dc.journal.pagination
23244-23250  
dc.journal.pais
Reino Unido  
dc.journal.ciudad
Cambridge  
dc.description.fil
Fil: Peña, Isabel. Universidad de Valladolid; España  
dc.description.fil
Fil: Kolesnikova, Lucie. Universidad de Valladolid; España  
dc.description.fil
Fil: Cabezas, Carlos. Universidad de Valladolid; España  
dc.description.fil
Fil: Bermudez, Celina. Universidad de Valladolid; España  
dc.description.fil
Fil: Berdakin, Matias. Universidad de Valladolid; España. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina  
dc.description.fil
Fil: Simao, Alcides. Universidad de Valladolid; España  
dc.description.fil
Fil: Alonso, Jose A.. Universidad de Valladolid; España  
dc.journal.title
Physical Chemistry Chemical Physics  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1039/c4cp03593c  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://pubs.rsc.org/en/Content/ArticleLanding/2014/CP/C4CP03593C  

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