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dc.contributor.author
Adam, Claudia Guadalupe  
dc.contributor.author
Bravo, Maria Virginia  
dc.contributor.author
Mancini, Pedro Maximo Emilio  
dc.date.available
2017-12-21T19:38:35Z  
dc.date.issued
2013-11  
dc.identifier.citation
Mancini, Pedro Maximo Emilio; Bravo, Maria Virginia; Adam, Claudia Guadalupe; Molecular solvent effect on the acidity constant of protic ionic liquids; Elsevier; Tetrahedron Letters; 55; 1; 11-2013; 148-150  
dc.identifier.issn
0040-4039  
dc.identifier.uri
http://hdl.handle.net/11336/31267  
dc.description.abstract
In this work how the microscopic properties of a molecular solvent affect the chemical environment of the protic ionic liquids (PILs) was analyzed. Using Reichardt’s dye as indicator of acidity, new acidity constant values for eight PILs (pKaPILs) were determined by spectrophotometric titration. Modifying the character hydrogen bonding donor of the molecular solvent it is possible to handle the PIL acid strength. Thus, we can turn basic PILs into acidic ones thereby the molecular solvent could be used as ‘additive’ for PILs, which allowed us to tune PILs design.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Elsevier  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
Molecular Solvent Effect  
dc.subject
Acidity Constant  
dc.subject
Protic Ionic Liquids  
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Microscopic Properties  
dc.subject
Reichardt’S Dye  
dc.subject
Pka  
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H Bonding Interact  
dc.subject.classification
Otras Ciencias Químicas  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
Molecular solvent effect on the acidity constant of protic ionic liquids  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2017-12-21T17:00:03Z  
dc.journal.volume
55  
dc.journal.number
1  
dc.journal.pagination
148-150  
dc.journal.pais
Países Bajos  
dc.journal.ciudad
Ámsterdam  
dc.description.fil
Fil: Adam, Claudia Guadalupe. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina  
dc.description.fil
Fil: Bravo, Maria Virginia. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe; Argentina  
dc.description.fil
Fil: Mancini, Pedro Maximo Emilio. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Química; Argentina  
dc.journal.title
Tetrahedron Letters  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0040403913018947  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.tetlet.2013.10.137  

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