Artículo

The structure of {[Co(pht)(bpy)(H2O)]·3H2O}n (pht is phthalate and bpy is 4,4'-bi­pyridine) and the role of solvent water clusters in structure stability

Harvey, Miguel Angel; Suarez, SebastianIcon ; Doctorovich, FabioIcon ; Cukiernik, Fabio DanielIcon ; Baggio, Ricardo Fortunato
Fecha de publicación: 03/2014
Editorial: International Union of Crystallography
Revista: Acta Crystallographica Section C: Structural Chemistry
ISSN: 2053-2296
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

The CoII cation in poly[[aqua(-benzene-1,2-dicarboxylato3 O1 ,O2 :O1 )(-4,40 -bipyridine-2 N:N0 )cobalt(II)] trihydrate], {[Co(C8H4O4)(C10H8N2)(H2O)]3H2O}n, is octahedrally coordinated by two N atoms of two 4,40 -bipyridine ligands, three O atoms from phthalate anions and a fourth O atom from a coordinated water molecule. The packing consists of planes of coordination polymers linked by hydrogen bonds mediated by three solvent water molecules; the linkage is achieved by the water molecules forming intricate oligomeric clusters which also involve the O atoms of the phthalate ligands.
Palabras clave: Crystal Structure , Water Structure
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
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URI: http://hdl.handle.net/11336/30703
DOI: http://dx.doi.org/10.1107/S2053229614006950
URL: http://scripts.iucr.org/cgi-bin/paper?S2053229614006950
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Articulos(INQUIMAE)
Articulos de INST.D/QUIM FIS D/L MATERIALES MEDIOAMB Y ENERGIA
Citación
Harvey, Miguel Angel; Suarez, Sebastian; Doctorovich, Fabio; Cukiernik, Fabio Daniel; Baggio, Ricardo Fortunato; The structure of {[Co(pht)(bpy)(H2O)]·3H2O}n (pht is phthalate and bpy is 4,4'-bi­pyridine) and the role of solvent water clusters in structure stability; International Union of Crystallography; Acta Crystallographica Section C: Structural Chemistry; 70; 5; 3-2014; 440-444
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