Artículo

Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids

Romanelli, Gustavo PabloIcon ; Tundo, Pietro; Aricó, Fabio; Vazquez, Patricia GracielaIcon
Fecha de publicación: 04/07/2010
Editorial: Elsevier Science
Revista: Catalysis Communications
ISSN: 1566-7367
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

This work describes the application of a multiphase system for the oxidation of alcohols to ketones or aldehydes, and the selective conversion of sulfides to sulfoxides or sulfones using Keggin-type heteropolyacids and hydrogen peroxide. Benzylic and secondary alcohols were oxidized to ketones or aldehydes at 70 °C in good yield and selectivity. Similarly, sulfides were converted to sulfoxides or sulfones at room temperature with high yields and selectivity.
Palabras clave: Multiphase System , Keggin Polyoxometalate , Hydrogen Peroxide , Alcohols
 
Archivos asociados
Thumbnail
 
Tamaño: 213.1Kb
Formato: PDF
.
Licencia
info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Atribución-NoComercial-SinDerivadas 2.5 Argentina (CC BY-NC-ND 2.5 AR)
Identificadores
URI: http://hdl.handle.net/11336/3023
DOI: http://dx.doi.org/10.1016/j.catcom.2010.06.015
URL: https://www.sciencedirect.com/science/article/pii/S1566736710001974
Colecciones
Articulos(CINDECA)
Articulos de CENTRO DE INV EN CS.APLICADAS "DR.JORGE J.RONCO"
Citación
Romanelli, Gustavo Pablo; Tundo, Pietro; Aricó, Fabio; Vazquez, Patricia Graciela; Multiphase oxidation of alcohols and sulfides with hydrogen peroxide catalyzed by heteropolyacids; Elsevier Science; Catalysis Communications; 11; 15; 4-7-2010; 1181-1184
Compartir
Altmétricas