Nucleophilic non-metal assited trifluoromethylation and perfluoroalkylation reactions of organic substrates

Nucleophilic trifluoromethylation and perfluoroalkylation reactions have been the outstanding approach during the last few decades to effect fluoroalkyl group addition or substitution reactions. In most instances, perfluoroalkyl-metal species participate at the beginning of the reactions. In this account, however, the latest nucleophilic non-metal assisted or uncatalyzed trifluoromethylation and perfluoroalkylation reactions of substrates bearing biological relevance will be discussed.

Palabras clave: Nucleophilic Trifluoromethylation , Fluoroform , Trimethylsilyltrifluoromethane , Fluorinated Sulfones , Fluorinated Sulfoxides , Fluorinated Sulfides

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Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Atribución-NoComercial-SinDerivadas 2.5 Argentina (CC BY-NC-ND 2.5 AR)

Identificadores

URI: http://hdl.handle.net/11336/30212

DOI: http://dx.doi.org/10.1016/j.jfluchem.2014.01.016

URL: http://www.sciencedirect.com/science/article/pii/S0022113914000268

Colecciones

Articulos(CIHIDECAR)
Articulos de CENTRO DE INVESTIGACIONES EN HIDRATOS DE CARBONO

Articulos(OCA HOUSSAY)
Articulos de OFICINA DE COORDINACION ADMINISTRATIVA HOUSSAY

Articulos(SEDE CENTRAL)
Articulos de SEDE CENTRAL

Citación

Barata Vallejo, Sebastian; Torviso, Maria del Rosario; Lantaño, Beatriz; Bonesi, Sergio Mauricio; Postigo, Jose Alberto; Nucleophilic non-metal assited trifluoromethylation and perfluoroalkylation reactions of organic substrates; Elsevier; Journal of Fluorine Chemistry; 161; 1-2014; 134-141

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