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dc.contributor.author
Estenoz, Diana Alejandra
dc.contributor.author
Vega, Jorge Ruben
dc.contributor.author
Oliva, Haydee
dc.contributor.author
Meira, Gregorio Raul
dc.date.available
2017-12-10T21:21:45Z
dc.date.issued
2002-12
dc.identifier.citation
Estenoz, Diana Alejandra; Vega, Jorge Ruben; Oliva, Haydee; Meira, Gregorio Raul; Grafting Efficiency in High-Impact Polystyrene by SEC Combined with Theoretical Predictions from a Polymerization-SEC Model; Taylor; Journal of Liquid Chromatography and Related Technologies; 25; 18; 12-2002; 2781-2793
dc.identifier.issn
1082-6076
dc.identifier.uri
http://hdl.handle.net/11336/30074
dc.description.abstract
In high-impact polystyrene (HIPS), the grafting efficiency (GE) is the mass of grafted styrene divided by the total mass of polymerized styrene. The GE along a prepolymerization was determined from the UV size exclusion chromatogram of the total polymer. The UV sensor at 254 nm "sees" only the free and grafted polystyrene (PS) chains, but not the polybutadiene (PB) chains. The data processing involves deconvoluting the UV chromatogram into the chromatograms of the free PS and grafted PS by means of polymerization-SEC model. The GE was determined after adjusting (by trial-and-3error) the predicted UV chromatogram to the measurement. A single adjustment parameter was used: the ratio between the rate of initiation to the monomer and the rate of initiation to the rubber. The method is quick and accurate, and the estimates were verified by solvent extraction-gravimetry. It is also possible to estimate the GE by deconvolution of the differential refractometer chromatogram. However, in this case a detector calibration is required, and the results are less accurate than when employing the UV sensor.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Taylor
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject.classification
Otras Ingeniería Química
dc.subject.classification
Ingeniería Química
dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
dc.title
Grafting Efficiency in High-Impact Polystyrene by SEC Combined with Theoretical Predictions from a Polymerization-SEC Model
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2017-11-24T13:44:35Z
dc.journal.volume
25
dc.journal.number
18
dc.journal.pagination
2781-2793
dc.journal.pais
Estados Unidos
dc.journal.ciudad
New York
dc.description.fil
Fil: Estenoz, Diana Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
dc.description.fil
Fil: Vega, Jorge Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
dc.description.fil
Fil: Oliva, Haydee. Universidad del Zulia; Venezuela
dc.description.fil
Fil: Meira, Gregorio Raul. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
dc.journal.title
Journal of Liquid Chromatography and Related Technologies
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1081/JLC-120014949
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