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dc.contributor.author
Lucío, María Isabel
dc.contributor.author
Pichler, Federica
dc.contributor.author
Ramírez, José Ramón
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de la Hoz, Antonio
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Sánchez Migallón, Ana
dc.contributor.author
Hadad, Caroline
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Quintana, Mildred
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Giulani, Angela
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Bracamonte, Maria Victoria
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Fierro, Jose L.G.
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Tavagnacco, Claudio
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Herrero, María Antonia
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Prato, Maurizio
dc.contributor.author
Vázquez, Ester
dc.date.available
2017-12-01T15:08:46Z
dc.date.issued
2016-05
dc.identifier.citation
Lucío, María Isabel; Pichler, Federica; Ramírez, José Ramón; de la Hoz, Antonio; Sánchez Migallón, Ana; et al.; Triazine-Carbon Nanotubes: New Platforms for the Design of Flavin Receptors; Wiley Vch Verlag; Chemistry- A European Journal; 22; 26; 5-2016; 8879-8888
dc.identifier.issn
0947-6539
dc.identifier.uri
http://hdl.handle.net/11336/29439
dc.description.abstract
The synthesis of functionalised carbon nanotubes as receptors for riboflavin (RBF) is reported. Carbon nanotubes, both single-walled and multi-walled, have been functionalised with 1,3,5-triazines and p-tolyl chains by aryl radical addition under microwave irradiation and the derivatives have been fully characterised by using a range of techniques. The interactions between riboflavin and the hybrids were analysed by using fluorescence and UV/Vis spectroscopic techniques. The results show that the attached functional groups minimise the p-p stacking interactions between riboflavin and the nanotube walls. Comparison of ptolyl groups with the triazine groups shows that the latter have stronger interactions with riboflavin because of the presence of hydrogen bonds. Moreover, the triazine derivatives follow the Stern–Volmer relationship and show a high association constant with riboflavin. In this way, artificial receptors in catalytic processes could be designed through specific control of the interaction between functionalised carbon nanotubes and riboflavin
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Wiley Vch Verlag
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Donor–Acceptor Systems
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Molecular Recognition
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Nanotubes
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Noncovalent Interactions
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Receptors
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Otras Ciencias Químicas
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Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
Triazine-Carbon Nanotubes: New Platforms for the Design of Flavin Receptors
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2017-06-05T14:49:21Z
dc.journal.volume
22
dc.journal.number
26
dc.journal.pagination
8879-8888
dc.journal.pais
Alemania
dc.journal.ciudad
Weinheim
dc.description.fil
Fil: Lucío, María Isabel. Universita Degli Studi Di Trieste; Italia. Universidad de Castilla-la Mancha; España
dc.description.fil
Fil: Pichler, Federica. Universidad de Castilla-la Mancha; España. Universita Degli Studi Di Trieste; Italia
dc.description.fil
Fil: Ramírez, José Ramón. Universidad de Castilla-la Mancha; España
dc.description.fil
Fil: de la Hoz, Antonio. Universidad de Castilla-la Mancha; España
dc.description.fil
Fil: Sánchez Migallón, Ana. Universidad de Castilla-la Mancha; España
dc.description.fil
Fil: Hadad, Caroline. Universita Degli Studi Di Trieste; Italia
dc.description.fil
Fil: Quintana, Mildred. Universidad Autonoma de San Luis Potosi;
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Fil: Giulani, Angela. Universita Degli Studi Di Trieste; Italia
dc.description.fil
Fil: Bracamonte, Maria Victoria. Universidad Nacional de Córdoba; Argentina. Universita Degli Studi Di Trieste; Italia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
dc.description.fil
Fil: Fierro, Jose L.G.. Instituto de Catlisis y Petroleoqumica. Madrid; España
dc.description.fil
Fil: Tavagnacco, Claudio. Universita Degli Studi Di Trieste; Italia
dc.description.fil
Fil: Herrero, María Antonia. Universidad de Castilla-la Mancha; España
dc.description.fil
Fil: Prato, Maurizio. Universita Degli Studi Di Trieste; Italia
dc.description.fil
Fil: Vázquez, Ester. Universidad de Castilla-la Mancha; España
dc.journal.title
Chemistry- A European Journal
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/chem.201600630
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/chem.201600630/abstract
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