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dc.contributor.author
Tomba, Juan Pablo
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dc.date.available
2017-11-10T20:56:44Z
dc.date.issued
2015-09-16
dc.identifier.citation
Tomba, Juan Pablo; Teaching Thermodynamics of Ideal Solutions: An Entropy-Based Approach To Help Students Better Understand and Appreciate the Subtleties of Solution Models; American Chemical Society; Journal Of Chemical Education; 92; 12; 16-9-2015; 2100-2105
dc.identifier.issn
0021-9584
dc.identifier.uri
http://hdl.handle.net/11336/27979
dc.description.abstract
The thermodynamic formalism of ideal solutions is developed in most of the textbooks postulating a form for the chemical potential of a generic component, which is adapted from the thermodynamics of ideal gas mixtures. From this basis, the rest of useful thermodynamic properties can be derived straightforwardly without further hypothesis. Although formally elegant, this approach to ideal solutions does not allow appreciation of subtle concepts embodied in the model such as requirements of molecular size and shape or the fact that equations that contain the universal gas constant (R) can be applied to describe liquid or solid solutions. As alternative, it is discussed here an approach centered on the behavior of the partial molar entropy of the component using the framework provided by the concept of accessible volume. It is shown that this way of presenting the topic allows a more natural flow and, particularly, analytical justification of all the hypothesis and ideas behind many fundamental solution models, including that of ideal solutions, with the extra advantage that it can almost entirely carried out from a macroscopic point of view.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
American Chemical Society
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dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Chemical Engineering
dc.subject
Graduate Education/Research
dc.subject
Materials Science
dc.subject
Physical Chemistry
dc.subject
Thermodynamics
dc.subject
Upper-Division Undergraduate
dc.subject.classification
Otras Ingeniería Química
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dc.subject.classification
Ingeniería Química
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dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
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dc.title
Teaching Thermodynamics of Ideal Solutions: An Entropy-Based Approach To Help Students Better Understand and Appreciate the Subtleties of Solution Models
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2017-11-10T15:39:23Z
dc.journal.volume
92
dc.journal.number
12
dc.journal.pagination
2100-2105
dc.journal.pais
Estados Unidos
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dc.journal.ciudad
Washington DC
dc.description.fil
Fil: Tomba, Juan Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
dc.journal.title
Journal Of Chemical Education
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dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/10.1021/acs.jchemed.5b00441
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/acs.jchemed.5b00441
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