Mostrar el registro sencillo del ítem

dc.contributor.author
Canales Gálvez, Ximena A.  
dc.contributor.author
Richezzi, Micaela  
dc.contributor.author
Bicalho, Hudson A.  
dc.contributor.author
Labadie, Natalia  
dc.contributor.author
Pellegrinet, Silvina Carla  
dc.contributor.author
Titi, Hatem M.  
dc.contributor.author
Howarth, Ashlee J.  
dc.date.available
2025-11-12T10:48:02Z  
dc.date.issued
2025-01  
dc.identifier.citation
Canales Gálvez, Ximena A.; Richezzi, Micaela; Bicalho, Hudson A.; Labadie, Natalia; Pellegrinet, Silvina Carla; et al.; Photoluminescent Properties of Tb-UiO-66 Metal–Organic Framework Analogues; American Chemical Society; Inorganic Chemistry; 64; 4; 1-2025; 1853-1859  
dc.identifier.issn
0020-1669  
dc.identifier.uri
http://hdl.handle.net/11336/275376  
dc.description.abstract
Three new analogues of Tb-UiO-66 with various functional groups (−F, −Br, −NH2) on the terephthalic acid linker of the metal–organic framework (MOF) are synthesized and characterized. The photoluminescent properties of these analogues, as well as Tb-UiO-66 and Tb-UiO-66-(OH)2, are studied and correlated to the calculated energies for the triplet (T1) states of each linker. The results show that the addition of electron withdrawing groups, such as −F and −Br, lead to higher T1 energies, resulting in quantum yields in the range of 6–31%. The addition of electron donating groups, on the other hand, lowers the T1 energy of the organic linker and inhibits energy transfer such that emission is not observed.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
American Chemical Society  
dc.rights
info:eu-repo/semantics/restrictedAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
CRYSTAL STRUCTURE  
dc.subject
ENERGY TRANSFER  
dc.subject
FUNCTIONAL GROUPS  
dc.subject
METAL ORGANIC FRAMEWOKS  
dc.subject
PHOTOLUMINISCENCE  
dc.subject.classification
Química Inorgánica y Nuclear  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
Photoluminescent Properties of Tb-UiO-66 Metal–Organic Framework Analogues  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2025-11-11T11:09:04Z  
dc.journal.volume
64  
dc.journal.number
4  
dc.journal.pagination
1853-1859  
dc.journal.pais
Estados Unidos  
dc.journal.ciudad
Washington  
dc.description.fil
Fil: Canales Gálvez, Ximena A.. Concordia University; Canadá  
dc.description.fil
Fil: Richezzi, Micaela. Concordia University; Canadá  
dc.description.fil
Fil: Bicalho, Hudson A.. Concordia University; Canadá  
dc.description.fil
Fil: Labadie, Natalia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; Argentina  
dc.description.fil
Fil: Pellegrinet, Silvina Carla. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Química Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario; Argentina  
dc.description.fil
Fil: Titi, Hatem M.. No especifíca;  
dc.description.fil
Fil: Howarth, Ashlee J.. Concordia University; Canadá  
dc.journal.title
Inorganic Chemistry  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acs.inorgchem.4c04523  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/acs.inorgchem.4c04523  

Archivos asociados
Tamaño: 900.4Kb
Formato: PDF
.