Artículo

Kinetic study of the selective catalytic hydrogenation of 1,3-butadiene in a mixture of n-butenes

Alves, Javier AlbertoIcon ; Bressa, Sergio Patricio; Martinez, Osvaldo MiguelIcon ; Barreto, Guillermo FernandoIcon
Fecha de publicación: 05/2012
Editorial: Korean Soc Industrial Engineering Chemistry
Revista: Journal Of Industrial And Engineering Chemistry
ISSN: 1226-086X
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

The selective hydrogenation in liquid phase of 1,3-butadiene in the presence of n-butenes, over acommercial Pd/Al2O3 catalyst of the egg-shell type was studied.Experiments were carried out in a batch reactor at 44 8C. Initial concentration were in the range of1%?2% of 1,3-butadiene, up to 10% of 1-butene, trans-2-butene and cis-2-butene. Partial hydrogenpressures ( pH2) were between 1 and 8 atm.Two kinetic models were proposed to fit the experimental data. Both models give an adequaterepresentation of the experimental data
Palabras clave: Selective hydrogenation , 1,3-butadiene , 1-butene , kinetic
 
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info:eu-repo/semantics/restrictedAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/272733
URL: https://www.sciencedirect.com/science/article/abs/pii/S1226086X12000433
DOI: https://doi.org/10.1016/j.jiec.2012.01.038
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Articulos(CINDECA)
Articulos de CENTRO DE INV EN CS.APLICADAS "DR.JORGE J.RONCO"
Citación
Alves, Javier Alberto; Bressa, Sergio Patricio; Martinez, Osvaldo Miguel; Barreto, Guillermo Fernando; Kinetic study of the selective catalytic hydrogenation of 1,3-butadiene in a mixture of n-butenes; Korean Soc Industrial Engineering Chemistry; Journal Of Industrial And Engineering Chemistry; 18; 4; 5-2012; 1353-1365
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