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dc.contributor.author
Schulz, Erica Patricia
dc.contributor.author
Durand, Guillermo Andrés
dc.date.available
2017-10-25T13:47:33Z
dc.date.issued
2016-01-21
dc.identifier.citation
Schulz, Erica Patricia; Durand, Guillermo Andrés; Equation oriented mixed micellization modeling based on asymmetric Margules-type formulations; Elsevier; Computers and Chemical Engineering; 87; 21-1-2016; 145-153
dc.identifier.issn
0098-1354
dc.identifier.uri
http://hdl.handle.net/11336/27057
dc.description.abstract
The determination of the composition of mixed micellar systems is a major problem since only the composition ofthe total micellar solution is accessible to the experimenter. A new approach is introduced in the present work based on Equation Oriented Optimization and Margules asymmetric formulations whichisnot restricted to thenumber of components and guarantees the applicability ofthe Gibbs–Duhem relation. The method is validated through its application to systems from literature and the quality of the solutions is tested with already published data and by comparison with other approaches. We do also show how excess properties can be predicted and that the excess entropy is not zero as assumed by the original regular and sub-regular solution theories.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.subject
Mixed Micelles
dc.subject
Margules Formulation
dc.subject
Regular Solution Theory
dc.subject
Mathematical Modeling
dc.subject.classification
Otras Ciencias Químicas
dc.subject.classification
Ciencias Químicas
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
dc.title
Equation oriented mixed micellization modeling based on asymmetric Margules-type formulations
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2017-10-09T16:42:01Z
dc.journal.volume
87
dc.journal.pagination
145-153
dc.journal.pais
Países Bajos
dc.journal.ciudad
Amsterdam
dc.description.fil
Fil: Schulz, Erica Patricia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
dc.description.fil
Fil: Durand, Guillermo Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
dc.journal.title
Computers and Chemical Engineering
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S009813541600003X
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.compchemeng.2015.12.026
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