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dc.contributor.author
Riechert, Verónica Mariel
dc.contributor.author
Failla, Marcelo Daniel
dc.contributor.author
Quinzani, Lidia Maria
dc.date.available
2017-10-23T21:15:10Z
dc.date.issued
2016-07
dc.identifier.citation
Riechert, Verónica Mariel; Failla, Marcelo Daniel; Quinzani, Lidia Maria; Effect of montmorillonite on the crystallization and thermal degradation of poly(propylene-coethylene- co-1-butene) nanocomposites; Sage Publications; Journal of Thermoplastic Composite Materials; 30; 6; 7-2016; 741-761
dc.identifier.issn
0892-7057
dc.identifier.uri
http://hdl.handle.net/11336/26967
dc.description.abstract
Polymeric nanocomposites based on poly(propylene-co-ethylene-co-1-butene) (PEBC) were elaborated by melt mixing using an organophilic montmorillonite (o-MMT) and maleated PEBC (PEBCg) as compatibilizer. The effect of clay concentration, PEBCg:o-MMT ratio, and grafting degree of the compatibilizer were studied. X-ray diffraction and scanning electron microscopy show formation of partially intercalated structures in all compatibilized composites with well-distributed small tactoids. According to the differential scanning calorimetry results, the anhydride groups of the compatibilizer have a marginal nucleating effect, while the o-MMT causes a slight decrease in the crystallization temperature of the polymer. PEBC presents the largest activation energy of crystallization (Eα), while the composites show lower Eα than their matrices. It is also observed that the rate of degradation of PEBC is not affected by the presence of PEBCg. The nanoclay, on the other hand, retards the decomposition process of the polymeric matrix in about 40°C and augments its rate of degradation approximately four times.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Sage Publications
dc.rights
info:eu-repo/semantics/restrictedAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Nanocomposites
dc.subject
Propylene Copolymer
dc.subject
Montmorillonite
dc.subject
Thermal Behavior
dc.subject.classification
Compuestos
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Ingeniería de los Materiales
dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
dc.title
Effect of montmorillonite on the crystallization and thermal degradation of poly(propylene-coethylene- co-1-butene) nanocomposites
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2017-10-09T15:34:44Z
dc.identifier.eissn
1530-7980
dc.journal.volume
30
dc.journal.number
6
dc.journal.pagination
741-761
dc.journal.pais
Estados Unidos
dc.journal.ciudad
Thousand Oak
dc.description.fil
Fil: Riechert, Verónica Mariel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
dc.description.fil
Fil: Failla, Marcelo Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
dc.description.fil
Fil: Quinzani, Lidia Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
dc.journal.title
Journal of Thermoplastic Composite Materials
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://journals.sagepub.com/doi/abs/10.1177/0892705715610409
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1177/0892705715610409
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1177/0892705715610409
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