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dc.contributor.author
Barluenga, José
dc.contributor.author
González Bobes, Francisco
dc.contributor.author
Murguia, Marcelo Cesar
dc.contributor.author
Ananthoju, Sreenivasa
dc.contributor.author
González, José
dc.date.available
2017-10-19T18:40:31Z
dc.date.issued
2004-07
dc.identifier.citation
Barluenga, José; González Bobes, Francisco; Murguia, Marcelo Cesar; Ananthoju, Sreenivasa; González, José; Bis(pyridine)iodonium Tetrafluoroborate (IPy2BF4): a versatile oxidizing reagent; Wiley VCH Verlag; Chemistry- A European Journal; 10; 17; 7-2004; 4206-4213
dc.identifier.issn
0947-6539
dc.identifier.uri
http://hdl.handle.net/11336/26833
dc.description.abstract
The use of bis(pyridine)iodonium tetrafluoroborate (IPy2BF4) as an oxidizing agent towards different types of alcohols is reported. The observed reactivity involves different reaction pathways, as a function both of the structures of the starting materials and of the experimental conditions. Interestingly, the title iodine-containing compound is capable of a tuneable reaction with simple cycloalkanols, providing straight and selective access either to ω-iodocarbonyl compounds or to ketones, a previously unreported and chemoselective range of oxidation potential. Furthermore, appropriate conditions for the preparation of aldehydes and esters from primary alcohols by easily performed experimental procedures were also established. The β-scission reactions of cycloalkanols and the α-oxidation processes of primary, secondary and benzylic alcohols are discussed.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Wiley VCH Verlag
dc.rights
info:eu-repo/semantics/restrictedAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Oxidations
dc.subject
Iodations
dc.subject
Iodonium
dc.subject
Bis Pyridine Iodonium
dc.subject.classification
Otras Ciencias Químicas
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Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
Bis(pyridine)iodonium Tetrafluoroborate (IPy2BF4): a versatile oxidizing reagent
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2017-10-17T14:09:07Z
dc.journal.volume
10
dc.journal.number
17
dc.journal.pagination
4206-4213
dc.journal.pais
Alemania
dc.description.fil
Fil: Barluenga, José. Universidad de Oviedo; España
dc.description.fil
Fil: González Bobes, Francisco. Universidad de Oviedo; España
dc.description.fil
Fil: Murguia, Marcelo Cesar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina. Universidad de Oviedo; España
dc.description.fil
Fil: Ananthoju, Sreenivasa. Universidad de Oviedo; España
dc.description.fil
Fil: González, José. Universidad de Oviedo; España
dc.journal.title
Chemistry- A European Journal
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1002/chem.200400136
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/chem.200400136/abstract


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