Artículo

A closer look at photochemical reactions of transition-metal compounds by time-resolved EPR

Martino, Debora MarcelaIcon ; Kleverlaan, C. J.; Slageren, J. van; Bussandri, A.; Willigen, H. van; Kiarie, C.
Fecha de publicación: 12/2004
Editorial: Springer Wien
Revista: Applied Magnetic Resonance
ISSN: 0937-9347
e-ISSN: 1613-7507
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

A review is given of applications of time-resolved Electron Paramagnetic Resonance (TREPR) in the field of photochemistry of transition metal compounds. The two main TREPR techniques used in these studies are described. A brief overview is given of Chemically Induced Dynamic Electron Polarization (CIDEP) mechanisms that can affect TREPR spectra and that can give insights into the mechanism of photochemical reactions. Following these background sections experimental results are presented. The discussion focuses in particular on the Fourier Transform EPR (FT-EPR) studies of photoinduced metal–alkyl bond homolysis reactions of a series of transition metal (Co, Ru, Re, Pt) complexes carried out by the authors.
 
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info:eu-repo/semantics/restrictedAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/26806
URL: https://link.springer.com/article/10.1007/BF03166579
DOI: http://dx.doi.org/10.1007/BF03166579
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Articulos de INST.DE DES.TECNOL.PARA LA IND.QUIMICA (I)
Citación
Martino, Debora Marcela; Kleverlaan, C. J.; Slageren, J. van; Bussandri, A.; Willigen, H. van; et al.; A closer look at photochemical reactions of transition-metal compounds by time-resolved EPR; Springer Wien; Applied Magnetic Resonance; 26; 4; 12-2004; 489-519
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