Propagation of NO2 originated in intense fires in the Paraná River Delta analyzed from satellite observations

Abstract

Wildfires in the Paraná River Delta started to be a common situation in the year 2008 and during the first years of the 2020´s decade: 2020, 2021, 2022. These fires affected natural areas, primarily the islands within the delta, situated in front of Rosario city (32.95°S, 60.67°W, 25 meters above sea level (m.a.s.l.)), Argentina. They mostly occur during the period between June and September each year and are more intense when a strong La Niña event is present. The aim of this study is to examine the association between the propagation of high intensity nitrogen dioxide (NO2) plumes and the significant fire events that occurred in the Paraná River Delta from 6 to 17 September2022. Satellite data of NO2 obtained from the TROPOspheric Monitoring Instrument (TROPOMI) on board the European Space Agency (ESA) Sentinel-5 Precursor satellite, air mass forward trajectories performed with The Hybrid Single-Particle Lagrangian IntegratedTrajectory model (HYSPLIT), Fire Radiative Power (FRP) data provided by Visible Infrared Imaging Radiometer Suite (VIIRS) on board The National Oceanic and Atmospheric Administration - 20 (NOAA-20) and Suomi National Polar-orbiting Partnership (SNPP) satellites, Aerosol Optical Depth (AOD) from VIIRS S-NPP and Smoke Injection Height from Multi-Angle Implementation ofAtmospheric Correction (MAIAC) Thermal Technique were employed. The trajectories followed by the air masses coming from the major fire sources locations nearby Rosario city and its surrounding area, were analyzed at altitudes of 20, 500, 1000, 1500 and 2000 m above ground level (AGL) in order to evaluate the impact of the NO2 clouds present in the atmosphere and carried by the winds, at different sites of Rosario and its adjacent region. The NO2 plumes has the potential to pose a significant health risk for this region, inhabited by an approximate population of one and a half million individuals. This risk is contingent upon the altitude where the highest levels of NO2 in the tropospheric column are found. Tropospheric vertical column densities (VCDs) of NO2 in the range of 4.68 x 10^14 to 1.66 x 10^16 molecules/cm2 were determined. The results indicate a robust correlation between elevated tropospheric NO2 VCD values and intense fires, as characterized by their FRP. Additionally, high tropospheric NO2 VCDs were observed to impact cities and towns located in close proximity to the fires. In particular, the unusually high tropospheric NO2 VCDs determined for the towns of Fighiera and Pueblo Esther, situated along the coast and near the Parana´ River Delta, are noteworthy. This is uncommon considering they are small towns inrural areas that typically have good air quality. The results regarding FRP, provided by VIIRS on board NOAA-20 and S-NPP satellites, indicate that the fire characterization of hotspots during the considered period had a mean value in the range of 20.17–21.47 MW. On specific days (12, 13 and 16 September 2022), the cumulative (total) daily values were very high, ranging from 2000 to 10000 MW. Furthermore, on 12 and 13 September 2022, the smoke aerosols did not reach significant altitudes in the atmosphere, remaining within the range of 0 to 1500 m AGL. During the fire period, AOD values close to 1 were observed within the fire plume. Notably, Puerto San Martín (0.27), San Lorenzo (0.22), and Ibarlucea (0.20) recorded higher average AOD values compared to other sites. The remaining sites generally exhibited lower average AOD values, with a slight distinction between rural locations (Pueblo Esther: 0.14 and Fighiera: 0.14) and the city center of Rosario (0.09).