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Artículo

Multiphase equilibria modeling with GCA-EoS: Part I: Carbon dioxide with the homologous series of alkanes up to 36 carbons

Gonzalez Prieto, MarianaIcon ; Sánchez, Francisco AdriánIcon ; Pereda, SelvaIcon
Fecha de publicación: 17/11/2015
Editorial: American Chemical Society
Revista: Industrial & Engineering Chemical Research
ISSN: 0888-5885
e-ISSN: 1520-5045
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:
Otras Ingeniería Química

Resumen

The Group Contribution with Association Equation of State (GCA-EoS) has been successfully applied to represent the global phase behavior of carbon dioxide mixtures with alkanes. Using a single set of parameters, the model is able to predict vapor−liquid and liquid−liquid equilibria of binary mixtures not included in the parametrization procedure. Special emphasis was set on describing the transformation between types of fluid phase behavior to reduce the jeopardy of predicting incorrect liquid split. This family of binary systems has been investigated in previous works; however, this is the first time that GCA-EoS was shown to be able to represent the transformation between types of phase behavior as the length of the alkyl chain increases. The model was tested against an experimental database covering C3−C36 alkanes, temperatures from 210 to 660 K, and pressures up to 400 bar. The wide range of conditions and the parametrization strategy are keys to develop a robust thermodynamic tool forpredicting multiphase behavior.
Palabras clave: Co2 , Gca-Eos , Multiphase
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/26166
URL: http://pubs.acs.org/doi/abs/10.1021/acs.iecr.5b03269
DOI: http://dx.doi.org/10.1021/acs.iecr.5b03269
Colecciones
Articulos(PLAPIQUI)
Articulos de PLANTA PILOTO DE INGENIERIA QUIMICA (I)
Citación
Gonzalez Prieto, Mariana; Sánchez, Francisco Adrián; Pereda, Selva; Multiphase equilibria modeling with GCA-EoS: Part I: Carbon dioxide with the homologous series of alkanes up to 36 carbons; American Chemical Society; Industrial & Engineering Chemical Research; 54; 49; 17-11-2015; 12415-12427
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