Silver Nanoplates: Theoretical and Experimental Characterization. Study of SERS Application

Abstract

Metal nanostructures have received significant attention in recent years owing to their peculiar physical and chemical properties, which span a wide range of practical applications in a variety of scientific and engineering fields. Herein, we report a study of the optical properties and application in the field enhancement of silver nanoplates (Ag-Nplates) obtained by two-step chemical synthesis. Optical Extinction Spectroscopy (OES), together with a detailed theoretical analysis of the experimental spectra, was used to characterize the size distribution, morphology, and optical spectral behavior of the obtained suspensions. These studies were complemented with shape and size distribution analyses using Transmission Electron Microscopy (TEM). It was observed by both techniques that these characteristics are related to the concentration of silver spherical nanoparticles (Ag-Seeds) added during the synthesis of Ag-Nplates. A decrease in the Ag-Seed amount produces an infrared shift of the main plasmon peak with respect to the neat Ag-Seeds suspension, which is related to the size growth of Ag-Nplates showing size distributions centered in the edge length range of 12-15 nm and 34-36 nm for the experimental spectra, whose plasmon peak positions are at 543 nm (higher Ag-Seeds concentration) and 815 nm (lower Ag-Seed concentration), respectively. The detection of Brilliant Blue (BB) by Surface-Enhanced Raman Spectroscopy (SERS) was successfully probed with the incorporation of Ag-Nplates in an agarose gel.