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dc.contributor.author
Bossolasco, Adriana Gabriela  
dc.contributor.author
Faragó, Eszter P.  
dc.contributor.author
Schoemaecker, Coralie  
dc.contributor.author
Fittschen, Christa  
dc.date.available
2017-10-06T15:54:15Z  
dc.date.issued
2013-12  
dc.identifier.citation
Bossolasco, Adriana Gabriela; Faragó, Eszter P.; Schoemaecker, Coralie; Fittschen, Christa; Rate constant of the reaction between CH3O2 and OH radicals; Elsevier Science; Chemical Physics Letters; 593; 12-2013; 7-13  
dc.identifier.issn
0009-2614  
dc.identifier.uri
http://hdl.handle.net/11336/26079  
dc.description.abstract
The rate constant of the reaction (R1)OH+CH3O2→products has been measured at 294 K by simultaneous coupling of Laser Induced Fluorescence (LIF) and cw-Cavity Ring Down Spectroscopy (cw-CDRS) to laser photolysis. OH radicals were generated by 248 nm photolysis of either H2O2 or O3 in the presence of H2O, CH3O2 radicals were generated simultaneously by photolysis of CH3I and their absolute concentrations were obtained by cw-CRDS. OH decays were measured under excess CH3O2 concentrations and a very fast rate constant of k1 = (2.8 ± 1.4) 1010 cm3 s1 was found independent of pressure at 50 and 100 Torr helium.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Elsevier Science  
dc.rights
info:eu-repo/semantics/openAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/  
dc.subject
Cavity Ring Down Spectroscopy  
dc.subject
Ch3oo Radicals  
dc.subject
Rate Constant  
dc.subject
Oh Radicals  
dc.subject.classification
Otras Ciencias Químicas  
dc.subject.classification
Ciencias Químicas  
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CIENCIAS NATURALES Y EXACTAS  
dc.title
Rate constant of the reaction between CH3O2 and OH radicals  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2017-10-05T20:37:40Z  
dc.journal.volume
593  
dc.journal.pagination
7-13  
dc.journal.pais
Países Bajos  
dc.journal.ciudad
Amsterdam  
dc.description.fil
Fil: Bossolasco, Adriana Gabriela. University Lille I; Francia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina  
dc.description.fil
Fil: Faragó, Eszter P.. University Lille I; Francia. University of Szeged; Hungría  
dc.description.fil
Fil: Schoemaecker, Coralie. University Lille I; Francia  
dc.description.fil
Fil: Fittschen, Christa. University Lille I; Francia  
dc.journal.title
Chemical Physics Letters  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.cplett.2013.12.052  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0009261413015406  

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