Artículo
Modelling the kinetics of UV/H2O2 oxidation of dichloroacetic acid
Zalazar, Cristina Susana
; Labas, Marisol Daniela
; Lovato, Maria Eugenia
; Brandi, Rodolfo Juan
; Cassano, Alberto Enrique
Fecha de publicación:
12/2007
Editorial:
IWA Publishing
Revista:
Water Science And Technology
ISSN:
0273-1223
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
The intrinsic reaction kinetics of the decomposition of dichloroacetic acid (DCA) using UV/H2O2 was studied. A complete mathematical model, including the effect of the absorbed radiation intensities and H2O2 concentration was developed. The results of the kinetic measurements were analysed using a complete mathematical model of the experimental device that was used for the laboratory operation (a differential reactor inside a recycle). In this way it was expected to obtain intrinsic kinetic parameters.Experimental data agree well with theoretical predictions esmploying just two kinetic parameters derived from the proposed reaction mechanism.
Palabras clave:
Uv/H2o2 Process
,
Dichloroacetic Acid
,
Kinetics Model
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Articulos(INTEC)
Articulos de INST.DE DES.TECNOL.PARA LA IND.QUIMICA (I)
Articulos de INST.DE DES.TECNOL.PARA LA IND.QUIMICA (I)
Citación
Zalazar, Cristina Susana; Labas, Marisol Daniela; Lovato, Maria Eugenia; Brandi, Rodolfo Juan; Cassano, Alberto Enrique; Modelling the kinetics of UV/H2O2 oxidation of dichloroacetic acid; IWA Publishing; Water Science And Technology; 55; 12; 12-2007; 31-35
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