Artículo
Solid-state spiro-rhodamines: Rational design of photoactive materials
Alday, Julieta Ruth
; Huck Iriart, Cristián
; Lagorio, María Gabriela
; González Lebrero, Mariano Camilo
; Suarez, Sebastian





Fecha de publicación:
08/2023
Editorial:
Wiley Blackwell Publishing, Inc
Revista:
Acta Crystallographica A
ISSN:
0108-7673
e-ISSN:
2053-2733
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
The system of study is a family of Spiro-Rhodamines (SRA), which are a derivative from the commercial Rhodamine dye with an aliphatic or aromatic amine. During the derivatization, a cyclization takes place, with loss of aromaticity, leading to a colourless and non-fluorescent CLOSE isomer (SF), which is thermally stable. Irradiation in the absorption band of this Isomer (around 350 nm) promotes the rupture of the C-N bond formed, recovering the Rhodamine´s chromophore and fluorophore in the OPEN isomer (OF). The change is thermally reversible, and the equilibria involves a protonation of the colourful isomer for stabilization. The system was characterized in solid state, by reflection, absorption and emission spectroscopy and X-ray diffraction, evaluating the changes produced after irradiating the corresponding SF with ultraviolet light for different derivatives. These characterizations have been performed in single crystal and thin films. Moreover, computational calculations were performed in order to explore the initial step of the light-induced opening mechanism.
Palabras clave:
PHOTOACTIVE MATERIALS
,
PHOTO-CRYSTALLOGRAPHY
Archivos asociados
Licencia
Identificadores
Colecciones
Articulos(INQUIMAE)
Articulos de INST.D/QUIM FIS D/L MATERIALES MEDIOAMB Y ENERGIA
Articulos de INST.D/QUIM FIS D/L MATERIALES MEDIOAMB Y ENERGIA
Citación
Alday, Julieta Ruth; Huck Iriart, Cristián; Lagorio, María Gabriela; González Lebrero, Mariano Camilo; Suarez, Sebastian; Solid-state spiro-rhodamines: Rational design of photoactive materials; Wiley Blackwell Publishing, Inc; Acta Crystallographica A; 79; a2; 8-2023; C743-C743
Compartir
Altmétricas