Artículo
A comparison of homogeneous and biphasic hydrogenation systems of macrocyclic lactones with in situ formed rhodium complexes
Fecha de publicación:
12/2008
Editorial:
Springer
Revista:
Reaction Kinetics And Catalysis Letters
ISSN:
0133-1736
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
Homogeneous and biphasic hydrogenation of avermectins catalyzed by rhodium complexes in situ formed from [RhCl(COD)]2 and triphenylphosphine or sulphonated arylphosphines, respectively, was studied under mild reaction conditions. Effects of adding TBAB and bis-QACs as phase transfer agents, Tween® 80 as non-ionic surfactant, β-cyclodextrin as inverse phase-transfer agent, and triphenylphosphine as co-ligand, are reported for the biphasic system.
Palabras clave:
Homogeneous Hydrogenation
,
Biphasic Hydrogenation
,
Rhodium
,
Avermectins
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Identificadores
Colecciones
Articulos(INCAPE)
Articulos de INST.DE INVEST.EN CATALISIS Y PETROQUIMICA "ING. JOSE MIGUEL PARERA"
Articulos de INST.DE INVEST.EN CATALISIS Y PETROQUIMICA "ING. JOSE MIGUEL PARERA"
Articulos(INTEC)
Articulos de INST.DE DES.TECNOL.PARA LA IND.QUIMICA (I)
Articulos de INST.DE DES.TECNOL.PARA LA IND.QUIMICA (I)
Citación
Cabrera, Maria Ines; Zgolicz, Patricia Daniela; Grau, Ricardo José Antonio; A comparison of homogeneous and biphasic hydrogenation systems of macrocyclic lactones with in situ formed rhodium complexes; Springer; Reaction Kinetics And Catalysis Letters; 93; 1; 12-2008; 175-185
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