Artículo

Thermal Stability of Peroxy Acyl Nitrates Formed in the Oxidation of CxF2x+1CH2C(O)H (x = 1,6) in the Presence of NO2

Henao Arboleda, Diana PatriciaIcon ; Malanca, Fabio ErnestoIcon ; Chiappero, Malisa SusanaIcon ; Argüello, Gustavo AlejandroIcon
Fecha de publicación: 06/2013
Editorial: American Chemical Society
Revista: Journal of Physical Chemistry A
ISSN: 1089-5639
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

The formation of CxF2x+1CH2C(O)OONO2 (x = 1,6) from the photooxidation of CxF2x+1CH2C(O)H (x = 1,6) in the presence of NO2 was investigated. The infrared spectrum of C6F13CH2C(O)OONO2 is reported for the first time, and thermal stability for both peroxynitrates at 295 K and 9.0 mbar is informed. Kinetic parameters (activation energy and pre-exponential factor) for CF3CH2C(O)OONO2 at 9.0 and 1000 mbar are: 108 ± 2 kJ/mol, 1.5 × 1015 and 114 ± 2 kJ/mol, 2.4 × 1016, respectively. A comparison is made between fluoro and hydrogenated peroxy acyl nitrates.
Palabras clave: Peroxynitrates
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/25237
URL: http://pubs.acs.org/doi/abs/10.1021/jp4003593
DOI: http://dx.doi.org/10.1021/jp4003593
Colecciones
Articulos(CCT - MAR DEL PLATA)
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - MAR DEL PLATA
Articulos(INFIQC)
Articulos de INST.DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Citación
Henao Arboleda, Diana Patricia; Malanca, Fabio Ernesto; Chiappero, Malisa Susana; Argüello, Gustavo Alejandro; Thermal Stability of Peroxy Acyl Nitrates Formed in the Oxidation of CxF2x+1CH2C(O)H (x = 1,6) in the Presence of NO2; American Chemical Society; Journal of Physical Chemistry A; 117; 17; 6-2013; 3625-3629
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