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dc.contributor.author
Safe, Yasmin Leila
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dc.contributor.author
Palenzona, Manuela
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dc.contributor.author
Lucchi, Leandro Damian
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dc.contributor.author
Domini, Claudia Elizabeth
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dc.contributor.author
Pereyra, Marcelo Tomas
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dc.date.available
2024-12-16T12:23:43Z
dc.date.issued
2023-07
dc.identifier.citation
Safe, Yasmin Leila; Palenzona, Manuela; Lucchi, Leandro Damian; Domini, Claudia Elizabeth; Pereyra, Marcelo Tomas; Multi-year monitoring of atmospheric dust fall as a sink for lead in an agro-industrial and petrochemical city of Argentina. Geo-accumulation and ecological risk assessment; Springer; Environmental Geochemistry And Health; 45; 7; 7-2023; 4817-4835
dc.identifier.issn
0269-4042
dc.identifier.uri
http://hdl.handle.net/11336/250582
dc.description.abstract
A multi-year monitoring data set of potentially harmful elements (PHEs), which are present in the chemical composition of atmospheric settleable particulate matter (SPM) in the urban, industrial and port areas in Bahía Blanca, was studied in order to assess potential ecological risk. The selected PHEs were metal elements of local and regional environmental importance (Cd, Cr, Cu, Ni, Pb, and Zn). Seventeen sampling campaigns were carried out between April 2013 and September 2019. After the microwave-assisted acid digestion of samples, the total contents of the PHEs were determined by ICP-OES. The annual dry deposition rate, the indexes associated with the potential ecological risk (RI) and the degree of geo-accumulation (Igeo) of each PHE were calculated. The results indicated that: (a) there are 3 groups (I, II, III) of PHEs with differentiated concentration levels, ranked I (Pb > Zn > Cu) > II (Cr ≈ Ni) > III (Cd) (p < 0.01) in all the studied areas; (b) the median of the total deposition rate was 1 mg cm−2. month−1 with a significant relative contribution of Pb; (c) a considerable increase in geo-accumulation of Pb indicated that SPM was functioning as a sink for Pb, and also reflected a significant progressive increase in the potential ecological risk in all sites (p < 0.01); and (d) there were chemometrically identified potential sources of Pb, Cu and Zn emissions that would be associated mainly to the resuspension of dust from geogenic, industrial and urban origin, and to a lesser extent, to other gaseous emissions of the industrial sector. This work highlights three major aspects of environmental assessment: (a) the value of continuous monitoring as an important tool to detect long-term trends; (b) the importance of the role of dust fall as a useful environmental indicator of lead geo-accumulation; and (c) the great utility of geo-accumulation and potential ecological risk indices as rapid quantitative assessment tools of environmental pollution.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Springer
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dc.rights
info:eu-repo/semantics/restrictedAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
AGRO-INDUSTRIAL AND PETROCHEMICAL CITY
dc.subject
ARGENTINA
dc.subject
ATMOSPHERIC PARTICULATE MATTER
dc.subject
POTENTIAL ECOLOGICAL RISK
dc.subject
POTENTIAL HARMFUL ELEMENTS
dc.subject.classification
Otras Ciencias de la Tierra y relacionadas con el Medio Ambiente
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dc.subject.classification
Ciencias de la Tierra y relacionadas con el Medio Ambiente
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dc.subject.classification
CIENCIAS NATURALES Y EXACTAS
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dc.title
Multi-year monitoring of atmospheric dust fall as a sink for lead in an agro-industrial and petrochemical city of Argentina. Geo-accumulation and ecological risk assessment
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2024-11-25T16:18:47Z
dc.journal.volume
45
dc.journal.number
7
dc.journal.pagination
4817-4835
dc.journal.pais
Alemania
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dc.description.fil
Fil: Safe, Yasmin Leila. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
dc.description.fil
Fil: Palenzona, Manuela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
dc.description.fil
Fil: Lucchi, Leandro Damian. Executive Technical Committee; Argentina
dc.description.fil
Fil: Domini, Claudia Elizabeth. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
dc.description.fil
Fil: Pereyra, Marcelo Tomas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina
dc.journal.title
Environmental Geochemistry And Health
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dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/10.1007/s10653-023-01539-2
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1007/s10653-023-01539-2
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