Artículo
Nucleophilic substitution of bromonorbornenes and derivatives by electron transfer reactions
Crespo Andrada, Karina Fernanda
; Peisino, Lucas Ernesto
; Güney, Murat; Dastan, Arif; Pierini, Adriana Beatriz
Fecha de publicación:
12/2012
Editorial:
Royal Society of Chemistry
Revista:
Organic & Biomolecular Chemistry
ISSN:
1477-0520
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
The photoinitiated substitution reactions of anti-7-bromobenzonorbornadiene (5), its syn isomer 6, exo–anti-13-bromobenzocyclobutanorbornene (7), syn-7-bromonorbornene (8) and bromonorbornane (9) with Me3Sn− and Ph2P− anions, in liquid ammonia, are here informed to occur with good yields of substitution. The stereochemical outcome is discussed in terms of calculations with the B3LYP functional and the 6-31+G* basis set; the solvent being included as a continuum through the PCM model. The experimental relative chemical reactivity of pairs of substrates toward a given anion is also presented.
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Articulos(INFIQC)
Articulos de INST.DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Articulos de INST.DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Citación
Crespo Andrada, Karina Fernanda; Peisino, Lucas Ernesto; Güney, Murat; Dastan, Arif; Pierini, Adriana Beatriz; Nucleophilic substitution of bromonorbornenes and derivatives by electron transfer reactions; Royal Society of Chemistry; Organic & Biomolecular Chemistry; 11; 6; 12-2012; 955-965
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