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dc.contributor.author
de Souza Garrido, Guilherme  
dc.contributor.author
Ribeiro Francisco, Lucas  
dc.contributor.author
Rabelo Neto, Raimundo C.  
dc.contributor.author
Xing, Yutao T.  
dc.contributor.author
Múnera Agudelo, John Fernando  
dc.contributor.author
Marcelle, Jonas  
dc.contributor.author
Jacobs, Gary  
dc.contributor.author
Noronha, Fabio B.  
dc.date.available
2024-12-05T10:14:36Z  
dc.date.issued
2023-09  
dc.identifier.citation
de Souza Garrido, Guilherme; Ribeiro Francisco, Lucas; Rabelo Neto, Raimundo C.; Xing, Yutao T.; Múnera Agudelo, John Fernando; et al.; The role of vanadium oxide species on the performance of Pd/VOx/SiO2 catalysts for HDO of phenol; Academic Press Inc Elsevier Science; Journal of Catalysis; 425; 9-2023; 155-169  
dc.identifier.issn
0021-9517  
dc.identifier.uri
http://hdl.handle.net/11336/249529  
dc.description.abstract
This work investigates the effect of vanadia species on the performance of Pd/VOx/SiO2 catalysts containing different vanadia loadings for HDO of phenol in the gas phase. in situ XANES experiments reveal the presence of a mixture of V2O4 and V4O7 species for all catalysts after reduction at 573 K. In situ XRD and XANES demonstrate that Pd particles and VOx species are in close contact, which is likely due to the presence of polymerized vanadate species, regardless of vanadia content, as shown by UV–Vis spectroscopy. This close contact promotes the selective hydrogenation of the C = O bond or the cleavage of the C-O bond, producing benzene. The strong interaction between the oxygen of the tautomer intermediate molecule and the oxygen vacancies associated with the presence of V3+ and V4+ cations is responsible for the deoxygenation activity of Pd/VOx/SiO2 catalysts.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Academic Press Inc Elsevier Science  
dc.rights
info:eu-repo/semantics/restrictedAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
Bio-oil  
dc.subject
Phenol  
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Hydrodeoxygenation  
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Vanadia  
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Metal-support interface  
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Otras Ciencias Químicas  
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Ciencias Químicas  
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CIENCIAS NATURALES Y EXACTAS  
dc.title
The role of vanadium oxide species on the performance of Pd/VOx/SiO2 catalysts for HDO of phenol  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2024-11-27T09:59:14Z  
dc.journal.volume
425  
dc.journal.pagination
155-169  
dc.journal.pais
Estados Unidos  
dc.description.fil
Fil: de Souza Garrido, Guilherme. National Institute of Technology; Brasil  
dc.description.fil
Fil: Ribeiro Francisco, Lucas. National Institute of Technology; Brasil  
dc.description.fil
Fil: Rabelo Neto, Raimundo C.. National Institute of Technology; Brasil  
dc.description.fil
Fil: Xing, Yutao T.. Universidade Federal Fluminense; Brasil  
dc.description.fil
Fil: Múnera Agudelo, John Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina  
dc.description.fil
Fil: Marcelle, Jonas. University of Texas at San Antonio; Estados Unidos  
dc.description.fil
Fil: Jacobs, Gary. University of Texas at San Antonio; Estados Unidos  
dc.description.fil
Fil: Noronha, Fabio B.. Université de Lille; Francia  
dc.journal.title
Journal of Catalysis  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0021951723002580  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.jcat.2023.06.016