Artículo
Phase behavior of model poly(butadiene 1-3)- block- dimethylsiloxane copolymers
Gomez, Leopoldo Raimundo
; Vega, Daniel Alberto
; Ninago, Mario Daniel
; Ciolino, Andrés Eduardo
; Villar, Marcelo Armando
; Valles, Enrique Marcelo
Fecha de publicación:
12/01/2015
Editorial:
Elsevier
Revista:
Polymer
ISSN:
0032-3861
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
Model diblock copolymers of poly(butadiene-1,3) and poly(dimethylsiloxane) (PB-b-PDMS) of different compositions were synthesized by the sequential anionic polymerization (high vacuum techniques) of butadiene 1,3 and hexamethyl(ciclotrisiloxane), (D3), monomers. The block copolymers were characterized by nuclear magnetic resonance (1H and 13C NMR), size-exclusion chromatography (SEC), Fourier Transform infrared spectroscopy (FTIR), and Small Angle X-ray Scattering (SAXS). SEC combined with 1H-NMR analysis indicate that the PB-b-PDMS copolymers exhibit molar masses between 5000 and 13000 g/mol, narrow polydispersity index (Mw/Mn), and chemical compositions ranging from low to intermediate siloxane content. According to SAXS experiments, at room temperature the model block copolymers present morphological arrangements that vary from disordered and body-centered-cubic packing of spheres, to hexagonally packed cylinders and lamellar structures.
Palabras clave:
Anionic Polymerization
,
Model Block Copolymers
,
Pb-B-Pdms
Archivos asociados
Licencia
Identificadores
Colecciones
Articulos(IFISUR)
Articulos de INSTITUTO DE FISICA DEL SUR
Articulos de INSTITUTO DE FISICA DEL SUR
Articulos(PLAPIQUI)
Articulos de PLANTA PILOTO DE INGENIERIA QUIMICA (I)
Articulos de PLANTA PILOTO DE INGENIERIA QUIMICA (I)
Citación
Gomez, Leopoldo Raimundo; Vega, Daniel Alberto; Ninago, Mario Daniel; Ciolino, Andrés Eduardo; Villar, Marcelo Armando; et al.; Phase behavior of model poly(butadiene 1-3)- block- dimethylsiloxane copolymers; Elsevier; Polymer; 59; 12-1-2015; 180-186
Compartir
Altmétricas