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Bis(oxalato)dioxovanadate(V) and Bis(oxalato)oxoperoxo-vanadate(V) Complexes: Spectroscopic Characterization and Biological Activity

Leon, Ignacio EstebanIcon ; Etcheverry, Susana BeatrizIcon ; Parajón Costa, Beatriz SusanaIcon ; Baran, Enrique JoséIcon
Fecha de publicación: 09-12 - 2013
Editorial: Humana Press
Revista: Biological Trace Element Research
Idioma: Inglés
URI: http://hdl.handle.net/11336/24494
http://dx.doi.org/10.1007/s12011-013-9787-4
https://link.springer.com/article/10.1007%2Fs12011-013-9787-4
Citación: Leon, Ignacio Esteban; Etcheverry, Susana Beatriz; Parajón Costa, Beatriz Susana; Baran, Enrique José; Bis(oxalato)dioxovanadate(V) and Bis(oxalato)oxoperoxo-vanadate(V) Complexes: Spectroscopic Characterization and Biological Activity; Humana Press; Biological Trace Element Research; 155; 2; 12-9-2013; 295-300

Abstract

Two structurally related vanadium(V) complexes, K3[VO2(C2O4)2]·3H2O and K3[VO(O2)(C2O4)2]·1/2H2O, were thoroughly characterized by infrared, Raman, and electronic spectroscopies. The effect of both complexes on the viability of the human MG-63 osteosarcoma cells was tested using the MTT assay. The monoperoxo complex shows a very strong antiproliferative activity (at 100-μM concentration, this complex diminished the cell viability ca. 80 %), whereas the dioxo complex was inactive.

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