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dc.contributor.author
Beltramone, Andrea Raquel
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dc.contributor.author
Resasco, D. E.
dc.contributor.author
Alvarez, W. E.
dc.contributor.author
Choudhary, T. V.
dc.date.available
2024-08-09T10:57:57Z
dc.date.issued
2008-08
dc.identifier.citation
Beltramone, Andrea Raquel; Resasco, D. E.; Alvarez, W. E.; Choudhary, T. V.; Simultaneous Hydrogenation of Multiring Aromatic Compounds over NiMo Catalyst; American Chemical Society; Industrial & Engineering Chemical Research; 47; 19; 8-2008; 7161-7166
dc.identifier.issn
0888-5885
dc.identifier.uri
http://hdl.handle.net/11336/242175
dc.description.abstract
Hydrogenation of six model feeds containing three-, two- and one-ring aromatic compounds was investigated to gain insights into the aromatic hydrogenation reaction chemistry over a commercial NiMo catalyst under practical reaction conditions. The hydrogenation reactivity of the aromatic compounds followed the following order: phenanthrene ~ two-ring aromatics >> one-ring aromatic. Comparison with previous studies revealed that the relative reactivity of the aromatic compounds is strongly influenced by the nature of the catalyst. Multiple component feed studies showed that phenanthrene and naphthalene strongly inhibited the tetralin hydrogenation rate, however naphthalene and tetralin had no appreciable effect on phenanthrene conversion. Langmuir-Hinshelwood type rate equations were used to describe the reaction kinetics with physically meaningful and well identified parameter values. The inhibition was attributed to competitive adsorption and was described in the kinetic model by adsorption terms which were obtained from the multicomponent feed experiments.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
American Chemical Society
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dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Simultaneous Hydrogenation
dc.subject
Multiring Aromatic Compounds
dc.subject
NiMo Catalyst
dc.subject.classification
Ingeniería Química
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dc.subject.classification
Ingeniería Química
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dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
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dc.title
Simultaneous Hydrogenation of Multiring Aromatic Compounds over NiMo Catalyst
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2024-08-08T15:45:50Z
dc.journal.volume
47
dc.journal.number
19
dc.journal.pagination
7161-7166
dc.journal.pais
Estados Unidos
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dc.description.fil
Fil: Beltramone, Andrea Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
dc.description.fil
Fil: Resasco, D. E.. Oklahoma State University; Estados Unidos
dc.description.fil
Fil: Alvarez, W. E.. No especifíca;
dc.description.fil
Fil: Choudhary, T. V.. No especifíca;
dc.journal.title
Industrial & Engineering Chemical Research
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dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/ie8004258
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1021/ie8004258
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