Mostrar el registro sencillo del ítem
dc.contributor.author
Beltramone, Andrea Raquel
![Se ha confirmado la validez de este valor de autoridad por un usuario](/themes/CONICETDigital/images/authority_control/invisible.gif)
dc.contributor.author
Crossley, S.
dc.contributor.author
Resasco, D. E.
dc.contributor.author
Alvarez, W. E.
dc.contributor.author
Choudhary, T. V.
dc.date.available
2024-08-09T10:57:44Z
dc.date.issued
2008-04
dc.identifier.citation
Beltramone, Andrea Raquel; Crossley, S.; Resasco, D. E.; Alvarez, W. E.; Choudhary, T. V.; Inhibition of the hydrogenation and hydrodesulfurization reactions by nitrogen compounds over NiMo/Al2O3; Springer; Catalysis Letters; 123; 3-4; 4-2008; 181-185
dc.identifier.issn
1011-372X
dc.identifier.uri
http://hdl.handle.net/11336/242173
dc.description.abstract
The inhibiting effect of nitrogen compounds on the hydrogenation of aromatic compounds and on the hydrodesulphurization (HDS) of dibenzothiophene (DBT) and 4,6-dimethyl dibenzothiophene (4,6DMDBT), has been systematically investigated over a commercial NiMo hydrotreating catalyst. Amongst the different nitrogen compounds considered, interestingly ammonia was found to have the strongest inhibition effect on hydrogenation as well as on hydrodesulfurization reactions. The inhibiting effects were found to increase in the order quinoline < tetrahydroquinoline < indole < indoline < ammonia for phenanthrene/tetralin hydrogenation and HDS reactions. The molecules with nitrogen atoms having higher negative Mulliken charges showed higher adsorption constants.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Springer
![Se ha confirmado la validez de este valor de autoridad por un usuario](/themes/CONICETDigital/images/authority_control/invisible.gif)
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
HDS
dc.subject
DBT
dc.subject
INHIBITION
dc.subject
KINETIC
dc.subject.classification
Ingeniería Química
![Se ha confirmado la validez de este valor de autoridad por un usuario](/themes/CONICETDigital/images/authority_control/invisible.gif)
dc.subject.classification
Ingeniería Química
![Se ha confirmado la validez de este valor de autoridad por un usuario](/themes/CONICETDigital/images/authority_control/invisible.gif)
dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
![Se ha confirmado la validez de este valor de autoridad por un usuario](/themes/CONICETDigital/images/authority_control/invisible.gif)
dc.title
Inhibition of the hydrogenation and hydrodesulfurization reactions by nitrogen compounds over NiMo/Al2O3
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2024-08-08T15:45:46Z
dc.journal.volume
123
dc.journal.number
3-4
dc.journal.pagination
181-185
dc.journal.pais
Alemania
![Se ha confirmado la validez de este valor de autoridad por un usuario](/themes/CONICETDigital/images/authority_control/invisible.gif)
dc.description.fil
Fil: Beltramone, Andrea Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina
dc.description.fil
Fil: Crossley, S.. Oklahoma State University; Estados Unidos
dc.description.fil
Fil: Resasco, D. E.. Oklahoma State University; Estados Unidos
dc.description.fil
Fil: Alvarez, W. E.. No especifíca;
dc.description.fil
Fil: Choudhary, T. V.. No especifíca;
dc.journal.title
Catalysis Letters
![Se ha confirmado la validez de este valor de autoridad por un usuario](/themes/CONICETDigital/images/authority_control/invisible.gif)
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007/s10562-008-9468-7
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1007/s10562-008-9468-7
Archivos asociados