Artículo
Synergistic enhancement of photo-assisted water splitting by mesoporous TiO2/NiFe LDH composite nanomaterials
Vensaus, Priscila
; Liang, Yunchang; Herrera, Facundo Carlos
; Soler Illia, Galo Juan de Avila Arturo
; Lingenfelder, Magalí Alejandra
Fecha de publicación:
03/2024
Editorial:
Pergamon-Elsevier Science Ltd
Revista:
International Journal of Hydrogen Energy
ISSN:
0360-3199
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
In the last decade, photo-assisted water splitting to generate hydrogen and oxygen has become a key process in the quest for clean energy technologies. In this context, the sluggish kinetics of the oxygen evolution reaction (OER) is still a limitation. The combination of an efficient electrocatalyst with a light-absorbing species can provide an output boost by the additional input of solar energy. In this work, we used ordered mesoporous nanocrystalline TiO2 thin films as a photoactive phase that contain embedded NiFe-based double-layered hydroxides (NiFe-LDH) catalysts for the OER in the mesopores. The structural and electrochemical properties of these materials were studied, taking into account the effect of the Ni:Fe ratio and concentration. Our results indicate that this material shows synergy in the photo-assisted water-splitting activity, as the total current is higher than the combined contributions of dark NiFeOx electrocatalysis and TiO2 photocurrent. Optimization of the NiFe ratio (9:1) and deposition time (60 s) produced an enhancement of up to 18 % in the total current at 1.50 V.
Palabras clave:
Photo -assisted water -splittin
,
Mesoporous thin film
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Articulos(SEDE CENTRAL)
Articulos de SEDE CENTRAL
Articulos de SEDE CENTRAL
Citación
Vensaus, Priscila; Liang, Yunchang; Herrera, Facundo Carlos; Soler Illia, Galo Juan de Avila Arturo; Lingenfelder, Magalí Alejandra; Synergistic enhancement of photo-assisted water splitting by mesoporous TiO2/NiFe LDH composite nanomaterials; Pergamon-Elsevier Science Ltd; International Journal of Hydrogen Energy; 59; 3-2024; 89-96
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