A comparative study of the effects of gas bubbles generated from hydrazine or/and water on the surface morphology and hydrophobicity of electrodeposited polymer films

The electrodeposition of polymeric films of a fluorene-bridged dicarbazole monomer containing linear polyfluorinated side chains is here investigated, with regard to the use of on-site electrochemically generated gas bubbles from hydrazine or water as soft template agent. The interconnected effects of the bubbles precursor and electrochemical parameters employed on the morphology and water wettability properties of the electrodeposited films are demonstrated. The use of N2H4 as a gas precursor proved to be a versatile, complementary alternative to water, which allows a finer tuning of the electrodeposited polymer film morphology.

Palabras clave: electrodeposited polymer films , hydrophobicity

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Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)

Identificadores

URI: http://hdl.handle.net/11336/232559

URL: https://www.sciencedirect.com/science/article/pii/S0013468623015876

DOI: http://dx.doi.org/10.1016/j.electacta.2023.143415

Colecciones

Articulos (IITEMA)
Articulos de INSTITUTO DE INVESTIGACIONES EN TECNOLOGIAS ENERGETICAS Y MATERIALES AVANZADOS

Citación

Possetto, David Ivan; Marzari, Gabriela Lorena; Pedraza Daza, Damian Antonio; Rueda, Héctor; Suchetti, Carlos Alberto; et al.; A comparative study of the effects of gas bubbles generated from hydrazine or/and water on the surface morphology and hydrophobicity of electrodeposited polymer films; Pergamon-Elsevier Science Ltd; Electrochimica Acta; 472; 12-2023; 1-7

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