Modeling and simulation of trickle bed reactors for the purification of 1-butene

Abstract

In this contribution, a mathematical model of an industrial trickle-bed reactor employed in the purification of a C4 cut by selective hydrogenation of acetylenic or dienes compounds to obtain high purity 1-butene is presented. A reaction network of ten reactions is included inthe model, with kinetics expressions and parameter estimation obtained from previous experimental studies on a commercial catalyst. Internal mass transfer resistances inthe catalyst particles are significant; therefore the reactiondiffusion equations must be solved. External mass transfer resistances in the liquid phase were retained, while those in the vapor phase were negligible. The model was employed to analyze the reactor behavior by varying the inlet molar flow rate of hydr ogen, the operating pressure, inlet temperature and the level of activity of the catalyst, taking into account its deactivation. It was demonstrated that the mass transfer resistances, inside and outside the catalyst particles, have a significant impact on the selectivity, but a careful operation of the reactor can improve the selectivity and extent the catalyst life. On the other hand, an alternative system was proposed, with two beds and a distributed input of H2, whichled to a significant improvement in the selectivity.