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dc.contributor.author
Bengoa, J. F.
dc.contributor.author
Campisi, S.
dc.contributor.author
Gervasini, A.
dc.contributor.author
Marchetti, Sergio Gustavo
dc.date.available
2024-03-11T12:53:45Z
dc.date.issued
2023-05
dc.identifier.citation
Bengoa, J. F.; Campisi, S.; Gervasini, A.; Marchetti, Sergio Gustavo; Mössbauer spectroscopy as a tool to predict the catalytic activity of the Fe3+ sites in an exchanged Fe/hydroxyapatite system; Springer; Journal of Nanoparticle Research; 25; 5; 5-2023; 1-15
dc.identifier.issn
1388-0764
dc.identifier.uri
http://hdl.handle.net/11336/230001
dc.description.abstract
Catalytic reactions, with iron species as the active phase, require a specific structural organization to achieve good activity and selectivity. Thus, the presence of isolated Fe3+ ions or nanoclusters, the capacity to produce Fe3+/Fe2+ couples, or certain chemisorb reactive molecules are necessary for different reactions. Therefore, if the presence of these structural properties can be demonstrated, it could be inferred that the system could be active in a determined reaction avoiding the screening of catalytic tests. In the present work, using Mössbauer spectroscopy, we have verified that exchanged Fe in hydroxyapatite can produce Fe3+/Fe2+ redox couples which are necessary to achieve good catalytic performances in the NOx, N2O, and NH3 abatement reactions. Besides, this technique allowed us to verify that isolated Fe3+ sites and Fe(III)xOy nanoclusters were able to chemisorb CO molecules. Therefore, it could be thought that Fe/hydroxyapatite system might be active in catalytic reactions in which adsorption and dissociation of CO are necessary.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Springer
dc.rights
info:eu-repo/semantics/restrictedAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
CATALYTIC
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CLUSTER ASSEMBLY
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FE
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MÖSSBAUER EFFECT
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NANOSTRUCTURE
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Otras Ciencias Químicas
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Ciencias Químicas
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CIENCIAS NATURALES Y EXACTAS
dc.title
Mössbauer spectroscopy as a tool to predict the catalytic activity of the Fe3+ sites in an exchanged Fe/hydroxyapatite system
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2024-03-11T11:59:44Z
dc.identifier.eissn
1572-896X
dc.journal.volume
25
dc.journal.number
5
dc.journal.pagination
1-15
dc.journal.pais
Alemania
dc.description.fil
Fil: Bengoa, J. F.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
dc.description.fil
Fil: Campisi, S.. Università degli Studi di Milano; Italia
dc.description.fil
Fil: Gervasini, A.. Università degli Studi di Milano; Italia
dc.description.fil
Fil: Marchetti, Sergio Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
dc.journal.title
Journal of Nanoparticle Research
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1007/s11051-023-05747-w
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