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dc.contributor.author
D'ippolito, Silvana Andrea
dc.contributor.author
Especel, Catherine
dc.contributor.author
Vivier, Laurence
dc.contributor.author
Epron, Florence
dc.contributor.author
Pieck, Carlos Luis
dc.date.available
2017-08-22T19:20:16Z
dc.date.issued
2014-01
dc.identifier.citation
D'ippolito, Silvana Andrea; Especel, Catherine; Vivier, Laurence; Epron, Florence; Pieck, Carlos Luis; Influence of the Brønsted acidity, SiO2/Al2O3 ratio and Rh-Pd content on the ring opening. Part II. Selective ring opening of methylcyclohexane; Elsevier; Applied Catalysis A: General; 469; 1-2014; 541-549
dc.identifier.issn
0926-860X
dc.identifier.uri
http://hdl.handle.net/11336/22800
dc.description.abstract
Monometallic and bimetallic Pd-Rh catalysts with various Rh/Pd atomic ratios (=0.5, 1 and 2) and a total metal charge of 1 wt% supported on SiO2-Al2O3(SIRAL 40, 20, 5) were studied for the ring opening of methylcyclohexane (MCH). The results were compared with those obtained previously for ring opening of decalin. It was found that the total acidity and the Brønsted acidity of the support have a higher influence on the activity for ring opening of naphthenic bicycles than on the activity for opening single rings. The influence of the metal charge is more important on the reaction of MCH. All the catalysts display a high MCH conversion, which increases with the reaction temperature. The bimetallic catalyst with the Rh/Pdratio equal to 2 and supported on SIRAL 40 has the highest yield to ring opening products.
dc.format
application/pdf
dc.language.iso
eng
dc.publisher
Elsevier
dc.rights
info:eu-repo/semantics/openAccess
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject
Ring Opening
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Bronsted Acidity
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Bimetallic Catalysts
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Rh-Pd
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Bifunctional Catalysts
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Methylcyclohexane
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Decalin
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Otras Ingeniería Química
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Ingeniería Química
dc.subject.classification
INGENIERÍAS Y TECNOLOGÍAS
dc.title
Influence of the Brønsted acidity, SiO2/Al2O3 ratio and Rh-Pd content on the ring opening. Part II. Selective ring opening of methylcyclohexane
dc.type
info:eu-repo/semantics/article
dc.type
info:ar-repo/semantics/artículo
dc.type
info:eu-repo/semantics/publishedVersion
dc.date.updated
2017-08-15T18:00:03Z
dc.journal.volume
469
dc.journal.pagination
541-549
dc.journal.pais
Países Bajos
dc.journal.ciudad
Amsterdam
dc.description.fil
Fil: D'ippolito, Silvana Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
dc.description.fil
Fil: Especel, Catherine. Universite de Poitiers. Laboratoire de Catalyse En Chimie Oranique; Francia
dc.description.fil
Fil: Vivier, Laurence. Universite de Poitiers. Laboratoire de Catalyse En Chimie Oranique; Francia
dc.description.fil
Fil: Epron, Florence. Universite de Poitiers. Laboratoire de Catalyse En Chimie Oranique; Francia
dc.description.fil
Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
dc.journal.title
Applied Catalysis A: General
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1016/j.apcata.2013.06.009
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0926860X13003396
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