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dc.contributor.author Cornaglia, Carolina Andrea
dc.contributor.author Tosti, Silvano
dc.contributor.author Sansovini, Mirko
dc.contributor.author Múnera Agudelo, John Fernando
dc.contributor.author Lombardo, Eduardo Agustin
dc.date.available 2017-08-18T20:09:50Z
dc.date.issued 2013-07
dc.identifier.citation Cornaglia, Carolina Andrea; Tosti, Silvano; Sansovini, Mirko; Múnera Agudelo, John Fernando; Lombardo, Eduardo Agustin; Novel catalyst for the WGS reaction in a Pd-membrane reactor; Elsevier; Applied Catalysis A: General; 462-463; 7-2013; 278-286
dc.identifier.issn 0926-860X
dc.identifier.uri http://hdl.handle.net/11336/22707
dc.description.abstract A Pt/La2O3·SiO2catalyst was synthesized and tested in the WGS reaction. Kinetic measurements werecarried out in a conventional fixed-bed reactor operated in differential mode while the stability test wasconducted in integral regime. The fresh and used catalysts were characterized through XRD, XPS, Ramanspectroscopy and H2chemisorption. The Pt(0.6 wt%)/La2O3(27 wt%)·SiO2catalyst showed high activityand WGS selectivity, no carbon formation and high stability. After use no changes were observed in thePt dispersion. The catalyst was also tested in a tubular Pd-Ag membrane reactor in order to gauge theperformance of this device using CO conversion, hydrogen recovery and H2production as parameters. Themembrane reactor experiments were performed between 673 and 723 K and at pressures ranging from100 kPa to 800 kPa. The low methanation activity was monitored in all cases. Under the best operatingconditions, a CO conversion of 98% and a hydrogen recovery of 90% were reached operating at 800 kPa inthe retentate side, and at 100 kPa in the permeate side.
dc.format application/pdf
dc.language.iso eng
dc.publisher Elsevier
dc.rights info:eu-repo/semantics/restrictedAccess
dc.rights.uri https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.subject Pt CATALYST
dc.subject STABILITY
dc.subject CH4 SELECTIVITY
dc.subject H2 PURIFICATION
dc.subject H2 purification
dc.subject.classification Otras Ingeniería Química
dc.subject.classification Ingeniería Química
dc.subject.classification INGENIERÍAS Y TECNOLOGÍAS
dc.title Novel catalyst for the WGS reaction in a Pd-membrane reactor
dc.type info:eu-repo/semantics/article
dc.type info:ar-repo/semantics/artículo
dc.type info:eu-repo/semantics/publishedVersion
dc.date.updated 2017-07-24T18:52:10Z
dc.journal.volume 462-463
dc.journal.pagination 278-286
dc.journal.pais Países Bajos
dc.journal.ciudad Amsterdam
dc.description.fil Fil: Cornaglia, Carolina Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones En Catalisis y Petroquímica "ing. Jose Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones En Catalisis y Petroquímica "ing. Jose Miguel Parera"; Argentina
dc.description.fil Fil: Tosti, Silvano. ENEA, Unità Tecnica Fusione; Italia
dc.description.fil Fil: Sansovini, Mirko. ENEA, Unità Tecnica Fusione; Italia
dc.description.fil Fil: Múnera Agudelo, John Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones En Catalisis y Petroquímica "ing. Jose Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones En Catalisis y Petroquímica "ing. Jose Miguel Parera"; Argentina
dc.description.fil Fil: Lombardo, Eduardo Agustin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones En Catalisis y Petroquímica "ing. Jose Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones En Catalisis y Petroquímica "ing. Jose Miguel Parera"; Argentina
dc.journal.title Applied Catalysis A: General
dc.relation.alternativeid info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0926860X1300210X
dc.relation.alternativeid info:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1016/j.apcata.2013.04.019


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    Articulos de INST.DE INVEST.EN CATALISIS Y PETROQUIMICA "ING. JOSE MIGUEL PARERA"

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info:eu-repo/semantics/restrictedAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)