Artículo

Influence of Molecular Parameters on Rate Constants of Thermal Dissociation/Recombination Reactions: The Reaction System CF4 ⇄ CF3 + F

Cobos, Carlos JorgeIcon ; Tellbach, Elsa; Sölter, Lars; Troe, Jürgen
Fecha de publicación: 02/2023
Editorial: American Chemical Society
Revista: Journal of Physical Chemistry A
ISSN: 1089-5639
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

The possibilities to extract incompletely characterized molecular parameters from experimental thermal rate constants for dissociation and recombination reactions are explored. The reaction system CF4 (+M) ⇄ CF3 + F (+M) is chosen as a representative example. A set of falloff curves is constructed and compared with the available experimental database. Agreement is achieved by minor (unfortunately not separable) adjustments of reaction enthalpy and collisional energy transfer parameters.
Palabras clave: CF4 ⇄ CF3 + F
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution 2.5 Unported (CC BY 2.5)
Identificadores
URI: http://hdl.handle.net/11336/226933
URL: https://pubs.acs.org/doi/10.1021/acs.jpca.3c00011
DOI: http://dx.doi.org/10.1021/acs.jpca.3c00011
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Articulos(INIFTA)
Articulos de INST.DE INV.FISICOQUIMICAS TEORICAS Y APLIC.
Citación
Cobos, Carlos Jorge; Tellbach, Elsa; Sölter, Lars; Troe, Jürgen; Influence of Molecular Parameters on Rate Constants of Thermal Dissociation/Recombination Reactions: The Reaction System CF4 ⇄ CF3 + F; American Chemical Society; Journal of Physical Chemistry A; 127; 7; 2-2023; 1697-1701
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