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dc.contributor.author
Politano, Fabrizio  
dc.contributor.author
Brydon, William P.  
dc.contributor.author
Leadbeater, Nicholas E.  
dc.date.available
2024-02-09T19:48:50Z  
dc.date.issued
2022-10  
dc.identifier.citation
Politano, Fabrizio; Brydon, William P.; Leadbeater, Nicholas E.; Oxidation of α-Trifluoromethyl and Nonfluorinated Secondary Alcohols to Ketones Using a Nitroxide Catalyst; Georg Thieme Verlag Kg; Synthesis-stuttgart; 55; 10; 10-2022; 1517-1524  
dc.identifier.issn
0039-7881  
dc.identifier.uri
http://hdl.handle.net/11336/226695  
dc.description.abstract
A methodology for the oxidation of E-trifluoromethyl alcohols to the corresponding trifluoromethyl ketones is presented. A catalytic quantity of a nitroxide is used, and potassium persulfate serves as the terminal oxidant. The methodology proves effective for aromatic, heteroaromatic, and conjugated alcohol substrates. It can be extended to nonfluorinated secondary alcohols and, in this case, can be applied to a range of aromatic, heteroaromatic, and aliphatic alcohols.  
dc.format
application/pdf  
dc.language.iso
eng  
dc.publisher
Georg Thieme Verlag Kg  
dc.rights
info:eu-repo/semantics/restrictedAccess  
dc.rights.uri
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/  
dc.subject
ALCOHOLS  
dc.subject
KETONES  
dc.subject
NITROXIDE  
dc.subject
OXIDATION  
dc.subject
PERSULFATE  
dc.subject
TRIFLUOROMETHYL KETONES  
dc.subject.classification
Química Orgánica  
dc.subject.classification
Ciencias Químicas  
dc.subject.classification
CIENCIAS NATURALES Y EXACTAS  
dc.title
Oxidation of α-Trifluoromethyl and Nonfluorinated Secondary Alcohols to Ketones Using a Nitroxide Catalyst  
dc.type
info:eu-repo/semantics/article  
dc.type
info:ar-repo/semantics/artículo  
dc.type
info:eu-repo/semantics/publishedVersion  
dc.date.updated
2024-02-09T12:21:00Z  
dc.journal.volume
55  
dc.journal.number
10  
dc.journal.pagination
1517-1524  
dc.journal.pais
Alemania  
dc.description.fil
Fil: Politano, Fabrizio. University of Connecticut; Estados Unidos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina  
dc.description.fil
Fil: Brydon, William P.. University of Connecticut; Estados Unidos  
dc.description.fil
Fil: Leadbeater, Nicholas E.. University of Connecticut; Estados Unidos  
dc.journal.title
Synthesis-stuttgart  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/url/http://www.thieme-connect.de/DOI/DOI?10.1055/s-0042-1752398  
dc.relation.alternativeid
info:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1055/s-0042-1752398  

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