Artículo
Indole HDN Using Iridium Nanoparticles Supported on Titanium Nanotubes
Ledesma, Brenda Cecilia Soledad
; Martinez, Maria Laura
; Gómez Costa, Marcos Bruno
; Beltramone, Andrea Raquel
Fecha de publicación:
11/2022
Editorial:
Springer
Revista:
Catalysis Letters
ISSN:
1011-372X
Idioma:
Inglés
Tipo de recurso:
Artículo publicado
Clasificación temática:
Resumen
The HDN of indole was studied over iridium modified titanate nanotube catalyst. Titanium nanotube was prepared by the alkaline hydrothermal method. Iridium was added by wetness impregnation. The activity was compared with Ir–TiO2 and commercial NiMo/Al2O3 catalysts. The catalysts prepared were characterized by X-ray diffraction (XRD), N2 adsorption isotherms, UV–Vis-DRS, FTIR, XPS, TEM, Py-FTIR and H2-Chemisorption. XRD, N2 isotherms and UV–vis-DRS confirmed the nanotube structure. The analysis showed that the mesoporous structure was maintained after Ir incorporation. The results showed that titanate nanotube as support significantly reduce the size of iridium crystallites and improves its dispersion considerably. Iridium titanate nanotube presented abundant and strong Brönsted acidity compared with TiO2 iridium catalyst. According a kinetic study, Ir–TNT was the most active catalyst for indole HDN, in mild conditions in a Batch reactor. The Brönsted acidity in synergic effect with Lewis acidity and hydrogenolysis capacity of iridium species were the responsible for the good activity.
Palabras clave:
CATALYSTS
,
HYDRODENITROGENATION
,
INDOLE
,
IRIDIUM
,
NANOTUBES
,
TITANIUM
Archivos asociados
Licencia
Identificadores
Colecciones
Articulos(CCT - CORDOBA)
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - CORDOBA
Articulos de CTRO.CIENTIFICO TECNOL.CONICET - CORDOBA
Citación
Ledesma, Brenda Cecilia Soledad; Martinez, Maria Laura; Gómez Costa, Marcos Bruno; Beltramone, Andrea Raquel; Indole HDN Using Iridium Nanoparticles Supported on Titanium Nanotubes; Springer; Catalysis Letters; 153; 10; 11-2022; 3111-3121
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