Artículo

Solid-gas reactions for nitroxyl (HNO) generation in the gas phase

Carrone, Guillermo AlejandroIcon ; Mazzeo, Agostina MaríaIcon ; Marceca, Ernesto JoséIcon ; Pellegrino, JuanIcon ; Suarez, SebastianIcon ; Zarenkiewicz, Jessica; Toscano, John P.; Doctorovich, FabioIcon
Fecha de publicación: 10/2021
Editorial: Elsevier Science Inc.
Revista: Journal of Inorganic Biochemistry
ISSN: 0162-0134
Idioma: Inglés
Tipo de recurso: Artículo publicado
Clasificación temática:

Resumen

We present a novel nitroxyl (HNO) generation method, which avoids the need of using a liquid system or extreme experimental conditions. This method consists of the reaction between a gaseous base and an HNO donor (Piloty's acid) in the solid phase, allowing the formation of gaseous HNO in a fast and economical way. Detection of HNO was carried out indirectly, measuring the nitrous oxide (N2O) byproduct of HNO dimerization using infrared spectroscopy, and directly, using mass spectrometry techniques and an electrochemical HNO sensor.
Palabras clave: GASEOUS , HNO , NITROXYL , PILOTY'S ACID
 
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info:eu-repo/semantics/openAccess Excepto donde se diga explícitamente, este item se publica bajo la siguiente descripción: Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Unported (CC BY-NC-SA 2.5)
Identificadores
URI: http://hdl.handle.net/11336/217185
URL: https://linkinghub.elsevier.com/retrieve/pii/S0162013421001823
DOI: http://dx.doi.org/10.1016/j.jinorgbio.2021.111535
Colecciones
Articulos(INQUIMAE)
Articulos de INST.D/QUIM FIS D/L MATERIALES MEDIOAMB Y ENERGIA
Citación
Carrone, Guillermo Alejandro; Mazzeo, Agostina María; Marceca, Ernesto José; Pellegrino, Juan; Suarez, Sebastian; et al.; Solid-gas reactions for nitroxyl (HNO) generation in the gas phase; Elsevier Science Inc.; Journal of Inorganic Biochemistry; 223; 10-2021; 1-20
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