Water Absorption Behavior of Oil Palm Empty Fruit Bunch (OPEFB) and Oil Palm Kernel Shell (OPKS) as Fillers in Acrylic Thermoplastic Composites

Abstract

In recent years, the use of oil palm wastes has been an interesting approach for the development of sustainable polymer matrix composites. Nevertheless, the water absorption behavior of these materials is one of the most critical factors for their performance over time. In this study, the water uptake characteristics of acrylic thermoplastic matrix composites reinforced separately with oil palm empty fruit bunch (OPEFB) and oil palm kernel shell (OPKS) were evaluated through immersion test in distilled water. The specimens of both composites were manufactured using the compression molding technique at three temperatures (80, 100, and 120 °C) using different particle sizes (425–600 and 600–850 µm). The composites, before and after the absorption test, were characterized by means of Fourier transform infrared spectroscopy, thermogravimetry, and scanning electron microscopy. The evaluation was complemented by the application of the Fickian diffusion model. Overall results showed that water absorption capacity decreased at a higher processing temperature and a larger particle size. In particular, it was observed that the type of reinforcement also influenced both water absorption and diffusivity. OPKS/acrylic and OPEFB/acrylic composites reached a maximum absorption of 77 and 86%, with diffusivities of 7.3 × 10−9 and 15.2 × 10−9 m2/min, respectively. Experimental evidence suggested that the absorption mechanism of the composites followed a non-Fickian model (n < 1.0).